Aureobasidium pullulans as a key for the preparation of optical purity (R)-2-(anthracen-9-yl)-2-methoxyacetic acid – The chiral auxiliary reagent in determination of absolute configuration

2015 ◽  
Vol 121 ◽  
pp. 28-31 ◽  
Author(s):  
Renata Kołodziejska ◽  
Marcin Wróblewski ◽  
Renata Studzińska ◽  
Aleksandra Karczmarska-Wódzka ◽  
Izabela Grela ◽  
...  
Keyword(s):  
Absolute Configuration ◽  
Aureobasidium Pullulans ◽  
Optical Purity ◽  
Chiral Auxiliary ◽  
Methoxyacetic Acid ◽  
Determination Of Absolute Configuration

scholarly journals Determination of absolute configuration of secondary alcohols using new chiral auxiliary and chemical shift calculation

2006 ◽  
Vol 47 (10) ◽  
pp. 1519-1523 ◽  
Author(s):  
Hajime Iwamoto ◽  
Yuka Kobayashi ◽  
Takefumi Kawatani ◽  
Masataka Suzuki ◽  
Yoshimasa Fukazawa
Keyword(s):  
Chemical Shift ◽  
Absolute Configuration ◽  
Chiral Auxiliary ◽  
Secondary Alcohols ◽  
Determination Of Absolute Configuration ◽  
Shift Calculation

Prismatomerin, a New Iridoid fromPrismatomeristetrandra. Structure Elucidation, Determination of Absolute Configuration, and Cytotoxicity

2007 ◽  
Vol 70 (8) ◽  
pp. 1339-1343 ◽  
Author(s):  
Karsten Krohn ◽  
Dietmar Gehle ◽  
Sujit Kumar Dey ◽  
Nilufar Nahar ◽  
Mohammed Mosihuzzaman ◽  
...  
Keyword(s):  
Absolute Configuration ◽  
Structure Elucidation ◽  
Determination Of Absolute Configuration

(-)-Strempeliopine, stereoselective total synthesis and the determination of absolute configuration

1986 ◽  
Vol 51 (8) ◽  
pp. 1731-1742 ◽  
Author(s):  
Josef Hájíček ◽  
Jan Trojánek
Keyword(s):  
Circular Dichroism ◽  
Total Synthesis ◽  
Absolute Configuration ◽  
Determination Of Absolute Configuration ◽  
Natural Base ◽  
The Absolute ◽  
Circular Dichroïsm

A synthesis of (±)-strempeliopine (II) is described, the key step of which is the stereoselective reductive rearrangement of 18-methylene-1,2-dehydroaspidospermidine (XI). The absolute configuration of the natural (-)-base II was determined as (2S, 7R, 20R, 21R) on the basis of its synthesis from (+)-18-methylenevincadifformine (XVII) the configuration of which was derived from a comparison of circular dichroism properties of bases with a β-anilinoacrylate chromophore. The biogenesis of the alkaloids of the schizozygane type is discussed.

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