Thermo-physical properties and corrosivity improvement of molten salts by use of nanoparticles for concentrated solar power applications: A critical review

2020 ◽  
Vol 314 ◽  
pp. 113807
Author(s):  
Hatem Ahmad Aljaerani ◽  
M. Samykano ◽  
A.K. Pandey ◽  
K. Kadirgama ◽  
R. Saidur
Author(s):  
Hani Tiznobaik ◽  
Donghyun Shin

In a concentrated solar power (CSP), high operating temperature (over 500 °C) is the key for enhancing the efficiency of the system. The operating temperature of the system mainly relies on thermal energy storage (TES) material. Existing TES materials such as mineral oil or paraffin wax cannot be applicable at high temperatures, since these materials are not thermally stable over 400 °C. However, very few materials are suitable and reliable for the high temperatures. Using molten salts (e.g., alkali nitrate, alkali carbonate, alkali chloride, etc.) as thermal energy storage material is an alternative way due to several benefits. They are cheap and environmentally safe compared with the conventional TES materials. They are thermally stable at higher temperatures (over 500 °C). However, their usage is limited due to low thermo-physical properties (e.g. Cp is less than 1.6 J/g°C). The low thermo-physical properties can be improved by dispersing nanoparticles into the salts. In this study, nanomaterials were synthesized by dispersing inorganic nanoparticles into ionic salts. Modulated differential scanning calorimeter (MDSC) was used to measure the heat capacity of the nanomaterials. Scanning electron microscopy (SEM) was used for material characteristic analysis. Hence, the application of the nanomaterials as thermal energy storage in a concentrated solar power was explored.


Energies ◽  
2019 ◽  
Vol 12 (3) ◽  
pp. 467 ◽  
Author(s):  
Xin Xiao ◽  
Gan Zhang ◽  
Yulong Ding ◽  
Dongsheng Wen

HITEC salt (NaNO2-NaO3-KNO3) and solar salt (NaO3-KNO3) are typical molten salts used in concentrated solar power. Adding nanoparticles is an effective method to improve the thermo-physical properties of pure salt. It is indispensable to experimentally study the rheological behaviours of salt seeded with nanoparticles, which can increase the specific heat capacity of pure salt. In this work, the viscosities of HITEC salt were measured with different shear rates in the temperature range of 200 °C to 450 °C firstly, while those of solar salt were measured in the temperature range of 250 °C to 500 °C. The experimental data showed reasonable agreement with the literature correlations, which verify the Newtonian behaviours of pure salts. The evolutions of the viscosities of nanocomposites in the same temperature range were measured and analysed, where the nanocomposites were synthesized with 1 wt.% or 2 wt.% Al2O3 nanopowder and graphene, respectively. Results showed that the addition of Al2O3 nanopowder had relatively little effect on viscosity, and the variations were about −35.4%~8.1% for the HITEC salt nanocomposites and −9.2%~68.1% for the solar salt nanocomposites. While graphene would apparently increase the viscosities of HITEC salt and solar salt, HITEC salt with the addition of graphene showed slight non-Newtonian fluid behaviour.


2021 ◽  
Vol 44 ◽  
pp. 103280
Author(s):  
Hatem Ahmad Aljaerani ◽  
M. Samykano ◽  
R. Saidur ◽  
A.K. Pandey ◽  
K. Kadirgama

2019 ◽  
Vol 2019 ◽  
pp. 1-10 ◽  
Author(s):  
Andrzej Bielecki ◽  
Sebastian Ernst ◽  
Wioletta Skrodzka ◽  
Igor Wojnicki

Concentrated solar power plants belong to the category of clean sources of renewable energy. The paper discusses the possibilities for the use of molten salts as storage in modern CSP plants. Besides increasing efficiency, it may also shift their area of application: thanks to increased controllability, they may now be used not only to cover baseload but also as more agile, dispatchable generators. Both technological and economic aspects are presented, with focus on the European energy sector and EU legislation. General characteristics for CSP plants, especially with molten salt storage, are discussed. Perspectives for their development, first of all in economic aspects, are considered.


Author(s):  
Syed Muhammad Mujtaba Rizvi ◽  
Yousof Nayfeh ◽  
Baha El Far ◽  
Donghyun Shin

Abstract Concentrated Solar Power (CSP) is one of the most efficient mega-scale renewable Energy sources. However, the overall cost of energy production is not viable for commercial usage and supplanting with fossil fuels or energy produced by nuclear ways. Its operational cost mainly lies in the electrical and thermal systems of the plant. The thermal system comprises of heat storage and heat transfer system. Any enhancement to heat storage or transfer system will directly reduce the cost of operation and increase the yield. Conventionally, oils stable up to 400C were used to transfer and store heat, however more recently, molten salts have been operational in the field for purpose of heat transfer but still, their thermal storage and conduction are limited. The current work explores the possibility of boosting the thermal storage capacity of molten salts through the latent heat of added phase change materials and increasing the specific heat at the same time by adding silica encapsulated zinc nanoparticles. We studied the advantage of adding coated Zn nano-sized particles to carbonate eutectic mixture for enhanced thermal energy storage and heat capacity enhancement. Zinc particles (40nm–60nm) obtained from the commercial sources were coated with silica shells using the solgel process under alkaline conditions. The nano-capsules were then dispersed in a mixture of carbonate salts. A differential scanning calorimeter was employed to characterize the thermal properties of the mixture. Tranmission electron miocroscopy was employed to characterize nanoparticles and electron diffraction Spectroscopy was performed to characterize materials and strcutures involved.


2020 ◽  
Vol 119 ◽  
pp. 109609 ◽  
Author(s):  
Amr Omar ◽  
Amir Nashed ◽  
Qiyuan Li ◽  
Greg Leslie ◽  
Robert A. Taylor

2012 ◽  
Vol 94 ◽  
pp. 174-181 ◽  
Author(s):  
Stéphanie Guillot ◽  
Abdessamad Faik ◽  
Aydar Rakhmatullin ◽  
Julien Lambert ◽  
Emmanuel Veron ◽  
...  

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