Synthesis, characterization, DFT calculations and biological studies of Mn(II), Fe(II), Co(II) and Cd(II) complexes based on a tetradentate ONNO donor Schiff base ligand

2017 ◽  
Vol 1134 ◽  
pp. 851-862 ◽  
Author(s):  
Laila H. Abdel-Rahman ◽  
Nabawia M. Ismail ◽  
Mohamed Ismael ◽  
Ahmed M. Abu-Dief ◽  
Ebtehal Abdel-Hameed Ahmed
2020 ◽  
Vol 17 (1) ◽  
pp. 0099
Author(s):  
Lekaa khalid Karem

This search includes the preparation of Schiff base ligand (SB) from condensation primary amine with vanillin. The new ligand was diagnosed by spectroscopic methods as Mass, NMR, CHN and FTIR. Ligand complexes were mixed from new (SB) and Anthranillic acid (A) with five metal (II) chlorides. The preparation and diagnosis were conducted by FTIR, CHN, UV-visible, molar conductivity, atomic absorption and magnetic moment. The octahedral geometrical shape of the complexes was proposed. The ligands and their new complexes were screened with two different types of bacteria.


2019 ◽  
Vol 48 (31) ◽  
pp. 11862-11871 ◽  
Author(s):  
Oleh Stetsiuk ◽  
Valentyn Synytsia ◽  
Svitlana R. Petrusenko ◽  
Vladimir N. Kokozay ◽  
Abdelkrim El-Ghayoury ◽  
...  

An unprecedented mixed-valence CoIII2MnII2MnIV2 cluster has been synthesized. Magnetochemical investigations combined with DFT calculations demonstrate the co-existence of antiferro- and ferromagnetic interactions within the MnIV2MnII2 core.


Author(s):  
Sze Koon Lee ◽  
Kong Wai Tan ◽  
Seik Weng Ng ◽  
Kah Kooi Ooi ◽  
Kok Pian Ang ◽  
...  

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