Physico-chemical aspects of polyethylene processing in an open mixer. Part 12: Heterogeneous kinetics of hydroxyl group formation at low temperature

2005 ◽  
Vol 89 (1) ◽  
pp. 175-187 ◽  
Author(s):  
F. Gugumus
Keyword(s):  
Low Temperature ◽  
Group Formation ◽  
Hydroxyl Group ◽  
Heterogeneous Kinetics ◽  
Physico Chemical ◽  
Kinetics Of

The low temperature aluminising kinetics of hot-work tool steels

2012 ◽  
Vol 67 (2) ◽  
pp. 133-139
Author(s):  
B. Matijević ◽  
I. Kumić ◽  
T. Belić
Keyword(s):  
Low Temperature ◽  
Tool Steels ◽  
Kinetics Of ◽  
Hot Work Tool Steels

The effect of origin and physico-chemical properties on the kinetics of reduction of mixed NiO-Fe2O3 oxides with hydrogen

1986 ◽  
Vol 51 (10) ◽  
pp. 2098-2108 ◽  
Author(s):  
Milan Pospíšil ◽  
Jan Topinka
Keyword(s):  
Mixed Oxides ◽  
Mutual Influence ◽  
Spinel Phase ◽  
Chemical Properties ◽  
Inhibitory Effect ◽  
Chemical Parameters ◽  
Physico Chemical ◽  
Preliminary Annealing ◽  
Kinetics Of ◽  
Kinetics Of Reduction

We investigated the effect of origin and some physico-chemical parameters on the kinetics of reduction with hydrogen of two series of mixed NiO-Fe2O3 oxides differing by their composition, the character of their precursors (mixed crystalline nitrates and coprecipitated hydroxides) and their decomposition temperature.This effect manifested itself by different magnitudes of specific surfaces of the mixed oxides and coherent regions of present phases as well as by different oxidizing abilities of the surface and differences in morphology and phase composition of corresponding samples in both series investigated. Nonlinear or nonmonotonous composition dependences of physico-chemical parameters investigated point to a mutual influence of individual components, which is also a function of the system origin and which modifies its reactivity during its reduction with hydrogen. The kinetics of the reduction was studied thermogravimetrically at 320-410 °C. The reduction of oxides of the hydroxide origin is catalytically accelerated by primarily reduced nickel, whereas in corresponding samples of the nitrate series, the total NiO is bound to the spinel phase and the reduction is delayed. Experimental IR spectra, the effect of preliminary annealing and DTA of the mixed oxides point to an inhibitory effect of water, which is constitutionally bound in trace admixtures of the goethite phase, on the kinetics of reduction of samples in the hydroxide series.

Kinetics of catalytic conversion of methanol at higher pressures

1980 ◽  
Vol 45 (12) ◽  
pp. 3402-3407 ◽  
Author(s):  
Jaroslav Bartoň ◽  
Vladimír Pour
Keyword(s):  
Low Temperature ◽  
Reaction Kinetics ◽  
Water Vapour ◽  
Kinetic Data ◽  
Catalytic Conversion ◽  
The Given ◽  
Kinetics Of

The course of the conversion of methanol with water vapour was followed on a low-temperature Cu-Zn-Cr-Al catalyst at pressures of 0.2 and 0.6 MPa. The kinetic data were evaluated together with those obtained at 0.1 MPa and the following equation for the reaction kinetics at the given conditions was derived: r = [p(CH3OH)p(H2O)]0.5[p(H2)]-1.3.

The Influence of Anthraquinone in Sulfite Delignification of Norway Spruce. 2. Phenolic Hydroxyl Group Formation

Holzforschung ◽  
1994 ◽  
Vol 48 (s1) ◽  
pp. 140-145 ◽  
Author(s):  
Hsin-Tai Chen ◽  
Masamitsu Funaoka ◽  
Yuan-Zong Lai
Keyword(s):  
Norway Spruce ◽  
Group Formation ◽  
Phenolic Hydroxyl ◽  
Hydroxyl Group
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