Sequence distribution affect the phase behavior and hydrogen bonding strength in blends of poly(vinylphenol-co-methyl methacrylate) with poly(ethylene oxide)

Polymer ◽  
2006 ◽  
Vol 47 (10) ◽  
pp. 3436-3447 ◽  
Author(s):  
Chen-Lung Lin ◽  
Wan-Chun Chen ◽  
Shiao-Wei Kuo ◽  
Feng-Chih Chang
Keyword(s):  
Hydrogen Bonding ◽  
Ethylene Oxide ◽  
Methyl Methacrylate ◽  
Phase Behavior ◽  
Bonding Strength ◽  
Sequence Distribution ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene ◽  
Hydrogen Bonding Strength

Sequence Distribution and Polydispersity Index Affect the Hydrogen-Bonding Strength of Poly(vinylphenol-co-methyl methacrylate) Copolymers

2005 ◽  
Vol 38 (15) ◽  
pp. 6435-6444 ◽  
Author(s):  
Chen-Lung Lin ◽  
Wan-Chun Chen ◽  
Chun-Syong Liao ◽  
Yi-Che Su ◽  
Chih-Feng Huang ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Methyl Methacrylate ◽  
Bonding Strength ◽  
Polydispersity Index ◽  
Sequence Distribution ◽  
Methacrylate Copolymers ◽  
Hydrogen Bonding Strength

scholarly journals Hierarchical Self-Assembled Structures from Diblock Copolymer Mixtures by Competitive Hydrogen Bonding Strength

Molecules ◽  
2018 ◽  
Vol 23 (9) ◽  
pp. 2242 ◽  
Author(s):  
Tzu-Chun Tseng ◽  
Shiao-Wei Kuo
Keyword(s):  
Hydrogen Bonding ◽  
Ethylene Oxide ◽  
Diblock Copolymer ◽  
Structure Transition ◽  
Reversible Addition ◽  
Poly Ethylene Oxide ◽  
Self Assembled ◽  
Poly Ethylene ◽  
Chain Transfer Polymerization ◽  
Hydrogen Bonding Strength

In this work we prepared poly(styrene–b–vinylphenol) (PS-b-PVPh) by sequential anionic living polymerization and poly(ethylene oxide-b-4-vinylpyridine) (PEO-b-P4VP) by reversible addition fragmentation chain transfer polymerization (RAFT) by using poly(ethylene oxide) 4-cyano-4-(phenylcarbonothioylthio)pentanoate (PEO-SC(S)Ph) as a macroinitiator with two hydrogen bonded acceptor groups. When blending with disordered PEO-b-P4VP diblock copolymer, we found the order-order self-assembled structure transition from lamellar structure for pure PS-b-PVPh to cylindrical, worm-like, and finally to PEO crystalline lamellar structures. Taking the advantage of the ΔK effect from competitive hydrogen bonding strengths between PVPh/P4VP and PVPh/PEO domains, it could form the hierarchical self-assembled morphologies such as core–shell cylindrical nanostructure.

scholarly journals Effect of Added Salt on Disordered Poly(ethylene oxide)-Block-Poly(methyl methacrylate) Copolymer Electrolytes

2021 ◽  
Vol 54 (3) ◽  
pp. 1414-1424
Author(s):  
Neel J. Shah ◽  
Sajjad Dadashi-Silab ◽  
Michael D. Galluzzo ◽  
Saheli Chakraborty ◽  
Whitney S. Loo ◽  
...  
Keyword(s):  
Ethylene Oxide ◽  
Methyl Methacrylate ◽  
Poly Methyl Methacrylate ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene ◽  
Methacrylate Copolymer ◽  
Added Salt
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