Efficient adsorption of a mixture of polycyclic aromatic hydrocarbons (PAHs) by Si–MCM–41 mesoporous molecular sieve

2017 ◽  
Vol 308 ◽  
pp. 434-441 ◽  
Author(s):  
José Arnaldo Santana Costa ◽  
Roberta Anjos de Jesus ◽  
Caio Marcio Paranhos da Silva ◽  
Luciane Pimenta Cruz Romão
2013 ◽  
Vol 5 (23) ◽  
pp. 6874 ◽  
Author(s):  
Chang-Feng Ou-Yang ◽  
Jin-Yu Liu ◽  
Hsien-Ming Kao ◽  
Jei-Hung Wang ◽  
Shi-Ping Liu ◽  
...  

2021 ◽  
Author(s):  
José Arnaldo S. Costa ◽  
Victor H. V. Sarmento ◽  
Luciane P. C. Romão ◽  
Caio M. Paranhos

Abstract Polycyclic aromatic hydrocarbons (PAHs) are one of the most recalcitrant pollutant originated from the burning of coal, petroleum, and other fossil fuels. The human exposure to PAHs may contribute to develop several carcinogenesis mechanisms. The aim of the present study was to develop a mixed matrix membrane (MMM) based on polyethersulfone (PES) and functionalized mesoporous material for the remediation of PAHs mixture by adsorption processes. MCM-41-based mesoparticles were obtained from biomass reuse of rice husk ash (RHA) and functionalized with p-aminobenzoic acid (PABA). The hydrothermal and casting methods were effective and sustainable in the preparation of PABA-MCM-41 and PES-based MMMs, respectively. PES-based MMMs presented an excellent distribution of the arrays incorporated and small-angle ordering. The absorption of PAHs was influenced by the incorporation of PABA-MCM-41 within the PES matrix.


2019 ◽  
Vol 64 (1) ◽  
pp. 55-67
Author(s):  
Vlad Pӑnescu ◽  
◽  
Mihaela Cӑtӑlina Herghelegiu ◽  
Sorin Pop ◽  
Mircea Anton ◽  
...  

2019 ◽  
Author(s):  
Yachu Du ◽  
Kyle Plunkett

We show that polycyclic aromatic hydrocarbon (PAH) chromophores that are linked between two five-membered rings can access planarized structures with reduced optical gaps and redox potentials. Two aceanthrylene chromophores were connected into dimer model systems with the chromophores either projected outward (2,2’-biaceanthrylene) or inward (1,1’-biaceanthrylene) and the optical and electronic properties were compared. Only the planar 2,2’-biaceanthrylene system showed significant reductions of the optical gaps (1 eV) and redox potentials in relation to the aceanthrylene monomer.<br>


Sign in / Sign up

Export Citation Format

Share Document