Phase change materials (PCMs) are promising for thermal energy storage applications, but low thermal conductivity limits their heat exchange rate with a working fluid. The nanofluid approach has been established as a method of thermal conductivity enhancement, but particle addition may have an adverse effect on specific energy storage capacity. Latent heat reduction beyond traditional theory has been observed experimentally for carbon nanotubes dispersed in paraffin wax. Nanofluid latent heat and effective thermal conductivity were analyzed to investigate the effects of particle addition on thermal properties affecting PCM energy storage performance. It is shown that particle diameter significantly impacts nanofluid latent heat, with smaller particles generating greater degrees of reduction, but has a negligible effect on thermal conductivity. A method to approximate nanofluid latent heat of fusion is presented, considering the diameter-dependent reduction observed.
Thermal conductivity of concrete at high temperatures for thermal energy storage applications: Experimental analysis
