CNT/PEDOT core/shell nanostructures as a counter electrode for dye-sensitized solar cells

2011 ◽  
Vol 161 (13-14) ◽  
pp. 1284-1288 ◽  
Author(s):  
Hyun-Jun Shin ◽  
Sang Soo Jeon ◽  
Seung Soon Im
2013 ◽  
Vol 117 (2) ◽  
pp. 927-934 ◽  
Author(s):  
Stafford W. Sheehan ◽  
Heeso Noh ◽  
Gary W. Brudvig ◽  
Hui Cao ◽  
Charles A. Schmuttenmaer

2009 ◽  
Vol 113 (43) ◽  
pp. 18515-18522 ◽  
Author(s):  
Natalie O. V. Plank ◽  
Ian Howard ◽  
Akshay Rao ◽  
Mark W. B. Wilson ◽  
Caterina Ducati ◽  
...  

2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
Luping Li ◽  
Cheng Xu ◽  
Yang Zhao ◽  
Kirk J. Ziegler

Dye-sensitized solar cells (DSSCs) hold great promise in the pursuit of reliable and cheap renewable energy. In this work, tin-doped indium oxide (ITO)-TiO2core-shell nanostructures are used as the photoanode for DSSCs. High-density, vertically aligned ITO nanowires are grown via a thermal evaporation method and TiO2is coated on nanowire surfaces via TiCl4treatment. It is found that high TiO2annealing temperatures increase the crystallinity of TiO2shell and suppress electron recombination in the core-shell nanostructures. High annealing temperatures also decrease dye loading. The highest efficiency of 3.39% is achieved at a TiO2annealing temperature of 500°C. When HfO2blocking layers are inserted between the core and shell of the nanowire, device efficiency is further increased to 5.83%, which is attributed to further suppression of electron recombination from ITO to the electrolyte. Open-circuit voltage decay (OCVD) measurements show that the electron lifetime increases by more than an order of magnitude upon HfO2insertion. ITO-TiO2core-shell nanostructures with HfO2blocking layers are promising photoanodes for DSSCs.


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