Heat capacity and thermodynamic functions of sphalerite: Implication to sulfide solid-state galvanic cell measurements

2016 ◽  
Vol 641 ◽  
pp. 14-23 ◽  
Author(s):  
V.M. Gurevich ◽  
V.O. Osadchii ◽  
V.B. Polyakov ◽  
K.S. Gavrichev ◽  
E.G. Osadchii
Keyword(s):  
Heat Capacity ◽  
Solid State ◽  
Thermodynamic Functions ◽  
Galvanic Cell

The thermodynamics of the divalent metal fluorides. I. Heat capacity of lead tetrafluorostannate, PbSnF4, from 10.3 to 352 K

1988 ◽  
Vol 66 (4) ◽  
pp. 549-552 ◽  
Author(s):  
Jane E. Callanan ◽  
Ron D. Weir ◽  
Edgar F. Westrum Jr.
Keyword(s):  
Phase Transition ◽  
Heat Capacity ◽  
Thermodynamic Functions ◽  
Adiabatic Calorimetry ◽  
Temperature Limit ◽  
Divalent Metal ◽  
Ion Conductor ◽  
Metal Fluorides ◽  
Fast Ion Conductor ◽  
Fast Ion

We have measured the heat capacity of the fast ion conductor PbSnF4 at 10.3 < T < 352 K by adiabatic calorimetry. Our results show anomalous values in the Cp,m in the region 300 < T < 352 K. These are associated with the α–β crystallographic transition reported at 353 K. Because the upper temperature limit of our cryostat is around 354 K, it was impossible to follow the phase transition to completion. A more subtle anomaly in the Cp,m was detected between 130 and 160 K. Standard molar thermodynamic functions are presented at selected temperatures from 5 to 350 K.

Recent advances in eye-safe Er:YAG solid-state heat-capacity technology

2012 ◽  
Author(s):  
Marc Eichhorn ◽  
Stefano Bigotta ◽  
Thierry Ibach
Keyword(s):  
Heat Capacity ◽  
Solid State ◽  
State Heat ◽  
Recent Advances

Heat capacity measurements on Sn2S3 and the thermodynamic functions of the tin sulfides

1980 ◽  
Vol 35 (2) ◽  
pp. 187-196 ◽  
Author(s):  
Heribert Wiedemeier ◽  
Frank Csillag ◽  
Umesh Gaur ◽  
Bernhard Wunderlich
Keyword(s):  
Heat Capacity ◽  
Thermodynamic Functions ◽  
Tin Sulfides ◽  
Heat Capacity Measurements
Sign in / Sign up

Export Citation Format

Share Document