Synthesis of kröhnke pyridines through iron-catalyzed oxidative condensation/double alkynylation/amination cascade strategy

Tetrahedron ◽  
2021 ◽  
pp. 132429
Author(s):  
Kovuru Gopalaiah ◽  
Renu Choudhary
Author(s):  
Kh. M. Minachev ◽  
N. Ya. Usachev ◽  
Yu. S. Khodakov ◽  
L. L. Kozlov ◽  
V. N. Udut ◽  
...  

2019 ◽  
Vol 39 (7) ◽  
pp. 2018
Author(s):  
Huanhuan Ju ◽  
Jiajing Sun ◽  
Xiaoliu Li ◽  
Hua Chen

2020 ◽  
Vol 44 (9-10) ◽  
pp. 557-565
Author(s):  
Zhenzhen Geng ◽  
Hong-yu Zhang ◽  
Guohui Yin ◽  
Yuecheng Zhang ◽  
Jiquan Zhao

The ionic liquid 1-methyl-3-(3-sulfopropyl)imidazolium chloride ([MIMPs]+Cl-) in combination with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and sodium nitrite (NaNO2) as a catalytic system demonstrates high efficiency in the one-pot two-step aerobic oxidative condensation of benzyl alcohols with 1,2-phenylenediamines to give benzimidazoles. Various benzimidazoles are obtained in good to excellent yields by this strategy.


ChemInform ◽  
2012 ◽  
Vol 43 (52) ◽  
pp. no-no
Author(s):  
Zhiyong Yang ◽  
Xiang Chen ◽  
Sizhuo Wang ◽  
Jidan Liu ◽  
Kai Xie ◽  
...  

2014 ◽  
Vol 70 (10) ◽  
pp. 1424-1427 ◽  
Author(s):  
José A. Brito ◽  
André Gutierres ◽  
Kevin Denkmann ◽  
Christiane Dahl ◽  
Margarida Archer

The ability to perform the very simple oxidation of two molecules of thiosulfate to tetrathionate is widespread among prokaryotes. Despite the prevalent occurrence of tetrathionate formation and its well documented significance within the sulfur cycle, little is known about the enzymes that catalyze the oxidative condensation of two thiosulfate anions. To fill this gap, the thiosulfate dehydrogenase (TsdA) enzyme from the purple sulfur bacteriumAllochromatium vinosumwas recombinantly expressed inEscherichia coli, purified and crystallized, and a crystallographic data set was collected. The crystals belonged to the monoclinic space groupC2, with unit-cell parametersa= 79.2,b= 69.9,c= 57.9 Å, β = 129.3°, contained one monomer per asymmetric unit and diffracted to a resolution of 1.98 Å.


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