Defluoridation of groundwater by a hybrid process combining adsorption and Donnan dialysis

Desalination ◽  
2002 ◽  
Vol 145 (1-3) ◽  
pp. 287-291 ◽  
Author(s):  
Hocine Garmes ◽  
Françoise Persin ◽  
Jacqueline Sandeaux ◽  
Gérald Pourcelly ◽  
Mohamed Mountadar
2019 ◽  
Vol 80 (1) ◽  
pp. 117-125 ◽  
Author(s):  
Ikhlass Marzouk Trifi ◽  
Beyram Trifi ◽  
Sirine Ben Ayed ◽  
Béchir Hamrouni

Abstract In this study the removal of phosphates from solution by Donnan dialysis and by adsorption onto calcium alginate beads were studied separately and then together. This hybrid process was conducted in order to benefit from each process, and it is an original and new combination. First, the Donnan dialysis process was performed with different parameters: the type of counter-ion, the concentration of the counter-ion, the initial phosphate concentration, the pH of the solution and the choice of anion-exchange membranes. Donnan dialysis achieved 68% and 12.5% phosphorus removal with AMX and AFN membranes respectively. Then a preliminary study into the adsorption of phosphate onto calcium alginate beads was carried out. A full factor design was applied in order to determine the effect of the main parameters and their mutual interactions for the adsorption process. The removal of phosphate onto calcium alginate beads reached 82.5%. Finally, coupling Donnan dialysis with adsorption onto calcium alginate beads for the removal of phosphate reached 89.5% with the AMX membrane. This hybrid process can be considered to be a solution for improving the contact time and for enhancing the removal of phosphate by 10% compared to adsorption onto calcium alginate.


Desalination ◽  
2021 ◽  
Vol 507 ◽  
pp. 114938
Author(s):  
Yangbo Qiu ◽  
Yayue Lv ◽  
Cong Tang ◽  
Junbin Liao ◽  
Huimin Ruan ◽  
...  

Author(s):  
Mehadi Aman ◽  
Yujiro Takeda ◽  
Kazuatsu Ito ◽  
Kaoru Yamamoto ◽  
Kohei Tanaka ◽  
...  

Author(s):  
Tamás Hergert ◽  
Béla Mátravölgyi ◽  
Róbert Örkényi ◽  
János Éles ◽  
Ferenc Faigl

AbstractA three-step batch-flow hybrid process has been developed for an expeditious synthesis of the enynol key intermediate of antifungal terbinafine. This procedure involves consecutive organometallic steps without the necessity of any in-line purification: after a metalation by n-butyllithium, a selective addition of the lithium salt was elaborated followed by a Grignard reaction resulting in a high yield of 6,6-dimethylhept-1-en-4-yn-3-ol. Moreover, as an alternative to tetrahydrofuran, cyclopentyl methyl ether was used as solvent implementing a safe, sustainable, yet selective synthetic process. Even on a laboratory-scale, the optimized batch-flow hybrid process had a theoretical throughput of 41 g/h. Furthermore, the newly developed process provides an efficient synthesis route to the key-intermediate, while making acrolein obsolete, minimizing side-products, and enabling safe and convenient scale-up.


Membranes ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 65
Author(s):  
Xueru Yan ◽  
Alexandre Favard ◽  
Stéphane Anguille ◽  
Marc Bendahan ◽  
Philippe Moulin

Membrane processes are promising methods to separate gases from feed streams without phase changing. A hybrid process, the combination of ionic liquids with a ceramic membrane (ILM), has been developed for humidity removal in a green continuous process. This new concept provides a more efficient and available ionic liquid (IL)-based membrane regeneration process, which just switches the moist feed stream to dry air. Furthermore, the ILM presents high stability and mechanical resistance during long-time operation. In addition, the influences of several operating parameters, including flow rate, temperature, absolute pressure, and feed concentration on process efficiency were investigated. The lower inlet flow rate was found to be favorable for drying humid air. Moreover, when the pressure increased, the mass of absorbed water was increased, while the feed concentration had no significant effects on the membrane separation performance. However, the operating temperature had a great effect on humidity removal. It is necessary to note that the processes at room temperature can limit the energy consumption. The absorbing process of ILM remained efficient after several absorption desorption cycles. Therefore, the new ILM hybrid process that has been developed has great potential for consecutive humidity removal processes.


Sign in / Sign up

Export Citation Format

Share Document