Mathematical models of the initial stage of the thermal degradation of poly(vinyl chloride)—IV. Influence of stereoisomery

1997 ◽  
Vol 33 (8) ◽  
pp. 1289-1294 ◽  
Author(s):  
B.B. Troitskii ◽  
L.S. Troitskaya
Keyword(s):  
Thermal Degradation ◽  
Mathematical Models ◽  
Vinyl Chloride ◽  
Poly Vinyl Chloride ◽  
Initial Stage

scholarly journals Construction of chain segment structure models, and effects on the initial stage of the thermal degradation of poly(vinyl chloride)

RSC Advances ◽  
2017 ◽  
Vol 7 (59) ◽  
pp. 37268-37275 ◽  
Author(s):  
Yin Lv ◽  
Jia Liu ◽  
Zhidong Luo ◽  
Heyun Wang ◽  
Zhong Wei
Keyword(s):  
Thermal Degradation ◽  
Vinyl Chloride ◽  
Chain Segment ◽  
Poly Vinyl Chloride ◽  
Initial Stage ◽  
Dehydrochlorination Reaction

Comparing two models, the dehydrochlorination reaction of PVC was predominantly initiated at the internal allylic chlorine sites, further promoting degradation.

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