Low-pressure electric discharge

1928 ◽  
Vol 205 (1) ◽  
pp. 103-111 ◽  
Author(s):  
C. Del Rosario
1897 ◽  
Vol 60 (359-367) ◽  
pp. 449-453 ◽  

In July of last year Professors Runge and Paschen (‘Phil Mag.,' 1895, [ii], vol. 40, pp. 297—302) announced their discovery that the spectrum of the gas from clèveite indicated the presence of two elements. They also stated that by means of a single diffusion through an asbestos plug, they had been able to effect a partial separation of the lighter constituent, which was characterised by the green glow which it gave under the influence of the electric discharge in a vacuum-tube, and which was represented in the spectrum by the series containing the green line, λ = 5015·6. Subsequently, at the meeting of the British Association at Ipswich, Professor Runge exhibited a tube containing the so-called green constituent; the colour of the glow differed strongly from that of an ordinary helium tube, but the gas contained in it was evidently at very low pressure, as phosphorescence was just commencing. Professor Runge has since acknowledged that the green effect in the helium tube may be produced by a change of pressure alone (‘Astrophysical Journal,’ January, 1896).


1994 ◽  
Vol 72 (11-12) ◽  
pp. 856-865 ◽  
Author(s):  
Hervé Abgrall ◽  
Evelyne Roueff ◽  
Françoise Launay ◽  
Jean-Yves Roncin

Spectral line positions and emission probabilities of the B′ 1Σu+ → X 1Σg+ and D 1Πu → X 1Σg+ band systems of molecular hydrogen have been calculated by solving a system of four coupled Schrödinger equations. A great number of rotational lines, emitted by a low-pressure electric discharge in H2, have been identified from 122 nm down to 78 nm. All the 69 bands of the B′ 1Σu+ → X 1Σg+ system and many high-J lines of 145 bands of the D 1Πu → X 1Σg+ system are reported for the first time. Improved molecular constants are derived for the (unperturbed) electronic excited state D 1Πu−.


1958 ◽  
Vol 30 (8) ◽  
pp. 1309-1314 ◽  
Author(s):  
R. C. Pitkethly

It has been found by Collie and Patterson that, after the passage of the electric discharge through pure hydrogen in a vacuum tube at low pressure, small quantities of helium and neon could be detected in the gas pumped out of the discharge tube. These gases were shown not to be present in the hydrogen which was let into the discharge tube. They must, then, either originate from—(i) occlusion of air in the glass or electrodes, or (ii) from the outer air during the experiment or the subsequent analysis, or (iii) be actually formed by some transmutation process due to the action of the discharge. In the latter case the seat of the effect of the discharge may be at the solid electrode, glass walls, or in the gas itself. The experiments of the above authors appear to show that:— (i) The gas did not originate from occlusion in the electrodes or glass walls, because these gave no such rare gases on solution and subsequent analysis of the gases.


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