Synthesis and characterization of a macrocycle containing different functional groups and its non-cyclic counterpart

2001 ◽  
Vol 318 (1-2) ◽  
pp. 152-158 ◽  
Author(s):  
Andrea Bencini ◽  
Mauro Formica ◽  
Vieri Fusi* ◽  
Claudia Giorgi ◽  
Luca Giorgi ◽  
...  
2005 ◽  
Vol 358 (13) ◽  
pp. 3592-3600 ◽  
Author(s):  
Takahiko Kojima ◽  
Hironori Kitaguchi ◽  
Yoshimitu Tachi ◽  
Mikio Yasutake ◽  
Yoshinori Naruta ◽  
...  

2009 ◽  
Vol 7 (1) ◽  
pp. 138-142 ◽  
Author(s):  
Ghasem Bardajee ◽  
Farnaz Jafarpour

AbstractIn this report, we described the synthesis and characterization of a variety of diaminotriarylmethane derivatives with dimethylamino functional groups. These compounds were synthesized by the tandem regio-selective electrophilic aromatic substitution reaction of N,N-dimethylaniline with aryl aldehydes to form the corresponding diaminotriarylmethane compounds. In our strategy, Bi(NO3)3 was used as a catalyst under solvent free conditions to afford the desired products in good to excellent yields.


2018 ◽  
Vol 25 (5) ◽  
Author(s):  
E. Gilbert ◽  
M. E. Taverna ◽  
M. F. Dieser ◽  
G. Morales ◽  
M. Spontón ◽  
...  

2012 ◽  
Vol 8 ◽  
pp. 967-976 ◽  
Author(s):  
Marco Caricato ◽  
Nerea Jordana Leza ◽  
Claudia Gargiulli ◽  
Giuseppe Gattuso ◽  
Daniele Dondi ◽  
...  

We report on the synthesis and characterization of novel shape-persistent, optically active arylamide macrocycles, which can be obtained using a one-pot methodology. Resolved, axially chiral binol scaffolds, which incorporate either methoxy or acetoxy functionalities in the 2,2' positions and carboxylic functionalities in the external 3,3' positions, were used as the source of chirality. Two of these binaphthyls are joined through amidation reactions using rigid diaryl amines of differing shapes, to give homochiral tetraamidic macrocycles. The recognition properties of these supramolecular receptors have been analyzed, and the results indicate a modulation of binding affinities towards dicarboxylate anions, with a drastic change of binding mode depending on the steric and electronic features of the functional groups in the 2,2' positions.


1989 ◽  
Vol 179 (2) ◽  
pp. 293-298 ◽  
Author(s):  
Tetsuya YOMO ◽  
Haruyo SAWAI ◽  
Itaru URABE ◽  
Yasuhiro YAMADA ◽  
Hirosuke OKADA

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