Substitution of the chloro ligands in cis-[CoCl2(2-C5H4NCO2Pri)2]: structural characterization of four mononuclear products showing both cis and trans configurations at Co(II)

2003 ◽  
Vol 346 ◽  
pp. 87-94 ◽  
Author(s):  
Ricard March ◽  
William Clegg ◽  
Robert A Coxall ◽  
Pilar González-Duarte
2011 ◽  
Vol 17 (46) ◽  
pp. 12834-12834
Author(s):  
Sunil K. Pandey ◽  
Ganesh F. Jogdand ◽  
João C. A. Oliveira ◽  
Ricardo A. Mata ◽  
Pattuparambil R. Rajamohanan ◽  
...  

2012 ◽  
Vol 2012 (13) ◽  
pp. 2656-2663 ◽  
Author(s):  
Awadut G. Giri ◽  
Ganesh F. Jogdand ◽  
Pattuparampil R. Rajamohanan ◽  
Sunil K. Pandey ◽  
Chepuri V. Ramana

2013 ◽  
Vol 93 (5) ◽  
pp. 923-931 ◽  
Author(s):  
Haiping Xin ◽  
Benhong Wu ◽  
Haohao Zhang ◽  
Caiyun Wang ◽  
Jitao Li ◽  
...  

Xin, H., Wu, B., Zhang, H., Wang, C., Li, J., Yang, B. and Li, S. 2013. Characterization of volatile compounds in flowers from four groups of sweet osmanthus ( Osmanthus fragrans ) cultivars. Can. J. Plant Sci. 93: 923–931. Headspace-solid-phase microextraction (HS-SPME) and gas chromatography-mass spectroscopy (GC-MS) were used to characterize the volatiles in flowers of four cultivar groups of sweet osmanthus (Osmanthus fragrans Lour.), including Thunbergii, Latifolius, Aurantiacus and Semperflorens Groups. A total of 72 volatiles were identified. Volatile compounds and their relative contents varied among the four groups or cultivars within each group. Briefly, β-ionone, cis-linalool oxide (furan), trans-linalool oxide (furan) and linalool were the most common volatiles in tested cultivars, while (E)-2-hexenal, (Z)-3-hexen-1-ol and hexanal were abundant in several cultivars. Principal component analysis showed that the Aurantiacus Group was rich in cis- and trans-linalool oxide (furan), whereas the Latifolius group had high levels of (E)-2-hexenal and (Z)-3-hexen-1-ol. Our results contribute to our understanding of the volatile composition and content in flowers from different osmanthus groups and will facilitate development of new osmanthus cultivars to meet requirements of the food and fragrance industries.


Minerals ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 347
Author(s):  
Xiaoli Wang ◽  
Yan Li ◽  
Hejing Wang

The structures of octahedral sheets of dioctahedral phyllosilicates show cis-vacant (cv) and trans-vacant (tv) configurations due to the different distributions of the octahedral cations over cis- and trans-sites. On the basis of the different dehydroxylation temperatures, a thermal analysis is an effective method used to identify the cv and tv configurations of an octahedral sheet in dioctahedral smectites. The proportions of cv and tv configurations were determined by fitting the derivative thermogravimetry (DTG) curves. A wide range of cv and tv proportions were detected in the samples. The dehydroxylation temperatures of samples consisting of cv configuration are about 150 to 200 °C higher than those consisting of tv configurations. The samples were classified as tv varieties when octahedral Fe3+ > 0.46 mol/FU, and the pure tv dioctahedral smectites were found when Fe3+ > 1.8 mol/FU. A clear linear relationship was found between the content of octahedral Fe3+ and Al3+ and the proportion of cv and tv configurations. The substitution of Al3+ by Fe3+ in the octahedral sheets is the main factor for the formation of tv varieties. There was no relationship detected between the layer charge density, octahedral Mg2+ content, and the proportion of tv and cv. The present results indicate that the iron content has a significant effect on the structure of the octahedral sheet.


Sign in / Sign up

Export Citation Format

Share Document