scholarly journals Catalytic mechanisms of glutamine synthetase enzymes. Studies with analogs of possible intermediates and transition states.

1976 ◽  
Vol 251 (23) ◽  
pp. 7530-7538
Author(s):  
F C Wedler ◽  
B R Horn
Biochemistry ◽  
1982 ◽  
Vol 21 (2) ◽  
pp. 354-363 ◽  
Author(s):  
Michael F. Dunn ◽  
Helmut Dietrich ◽  
Alastair K. H. MacGibbon ◽  
Steven C. Koerber ◽  
Michael Zeppezauer

Author(s):  
W. Kunath ◽  
E. Zeitler ◽  
M. Kessel

The features of digital recording of a continuous series (movie) of singleelectron TV frames are reported. The technique is used to investigate structural changes in negatively stained glutamine synthetase molecules (GS) during electron irradiation and, as an ultimate goal, to look for the molecules' “undamaged” structure, say, after a 1 e/Å2 dose.The TV frame of fig. la shows an image of 5 glutamine synthetase molecules exposed to 1/150 e/Å2. Every single electron is recorded as a unit signal in a 256 ×256 field. The extremely low exposure of a single TV frame as dictated by the single-electron recording device including the electron microscope requires accumulation of 150 TV frames into one frame (fig. lb) thus achieving a reasonable compromise between the conflicting aspects of exposure time per frame of 3 sec. vs. object drift of less than 1 Å, and exposure per frame of 1 e/Å2 vs. rate of structural damage.


2017 ◽  
Vol 43 (9) ◽  
pp. 1410 ◽  
Author(s):  
Xiao-Chun WANG ◽  
Hao-Ran ZHANG ◽  
Yi-Hao WEI ◽  
Xi-Ting JIA ◽  
Ming-Xin GU ◽  
...  

2020 ◽  
Vol 17 (3) ◽  
pp. 224-233
Author(s):  
Xun Zhu ◽  
Chen Jian ◽  
Xiuqin Zhou ◽  
Abdullah M. Asiri ◽  
Khalid A. Alamry ◽  
...  

The pyrolysis of methyl alkyl esters I to III and dithioesters IV to VI were theoretically calculated. All possible pyrolysis paths were considered. Both esters and dithioesters presented three potential paths via six-, four- and five-membered ring transition states, respectively. The calculation processes were calculated using MP2/6-31G(d) set. In-depth theoretical analyses were also presented, including NBO related analyses, synchronicities, and charge distributions, to reveal the detailed pyrolysis process.


2013 ◽  
Vol 12 (7) ◽  
pp. 900-913 ◽  
Author(s):  
Hans-Gert Bernstein ◽  
Anne Tausch ◽  
Rebecca Wagner ◽  
Johann Steiner ◽  
Patrick Seeleke ◽  
...  

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