Raman studies of the anionic sublattice vibrations in (C5H5NH)6Bi4Cl18

2002 ◽  
Vol 614 (1-3) ◽  
pp. 333-338 ◽  
Author(s):  
J Tarasiewicz ◽  
R Jakubas ◽  
J Baran
Keyword(s):  
Anionic Sublattice

scholarly journals Understanding cation-disordered rocksalt oxyfluoride cathodes

2021 ◽  
Vol 9 (12) ◽  
pp. 7826-7837
Author(s):  
Dongchang Chen ◽  
Juhyeon Ahn ◽  
Ethan Self ◽  
Jagjit Nanda ◽  
Guoying Chen
Keyword(s):  
Transition Metal ◽  
Failure Mechanism ◽  
Cathode Materials ◽  
Atomic Level ◽  
Cationic Sublattice ◽  
Anionic Sublattice ◽  
Oxygen Fluorine

A “concerted-densification” based failure mechanism, involving atomic-level changes in both transition-metal cationic sublattice and oxygen/fluorine anionic sublattice, is proposed for the degradation of F-DRX cathode materials.

scholarly journals Synthesis and structural studies of a new complex ofcatena-poly[p-anisidinium [[diiodidobismuthate(III)]-di-μ-iodido] dihydrate]

2015 ◽  
Vol 71 (11) ◽  
pp. 1352-1355
Author(s):  
Mohamed El Mehdi Touati ◽  
S. Elleuch ◽  
Habib Boughzala
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Bonds ◽  
Hybrid Material ◽  
Room Temperature ◽  
Water Molecules ◽  
Structural Studies ◽  
Slow Evaporation ◽  
Inorganic Hybrid ◽  
Anionic Sublattice ◽  
Inorganic Layers

A new organic–inorganic hybrid material, {(C7H10NO)[BiI4]·2H2O}n, has been synthesized by slow evaporation of an aqueous solution at room temperature. The anionic sublattice of the crystal is built up by [BiI6] octahedra sharing edges. The resulting zigzag chains extend along thea-axis direction and are arranged in a distorted hexagonal rod packing. Thep-anisidinium cations and the water molecules are located in the voids of the anionic sublattice. The cations are linked to each other through N—H...O hydrogen bonds with the water molecules, and also through weaker N—H...I interactions to the anionic inorganic layers.

Perovskite hetero-anionic-sublattice interfaces for optoelectronics and nonconventional electronics

Nanoscale ◽  
2020 ◽  
Vol 12 (13) ◽  
pp. 7263-7272
Author(s):  
Dali Cheng ◽  
Deying Kong ◽  
Xing Sheng ◽  
Lan Yin ◽  
Huanglong Li
Keyword(s):  
Oxygen Sublattice ◽  
Anionic Sublattice ◽  
Emergent Phenomena

Perovskite hetero-anionic-sublattice interfaces can provide a new platform for emergent phenomena that may or may not have homo-oxygen-sublattice interface analogues.

Electronic properties of substitutions in the YBa2Cu3O7 anionic sublattice

1990 ◽  
Vol 172 (1-2) ◽  
pp. 149-154 ◽  
Author(s):  
S.N. Molotkov ◽  
S.S. Nazin ◽  
I.S. Smirnova ◽  
V.V. Tatarskii
Keyword(s):  
Electronic Properties ◽  
Anionic Sublattice

Ion transport in salts orientationally disordered in anionic sublattice

2011 ◽  
Vol 188 (1) ◽  
pp. 78-82 ◽  
Author(s):  
N.F. Uvarov ◽  
A.A. Iskakova ◽  
A.S. Ulihin ◽  
N.N. Medvedev ◽  
A.V. Anikeenko
Keyword(s):  
Ion Transport ◽  
Anionic Sublattice

Crystal and Molecular Structure of 1,2,4-Triazolium Chloride and its Salt with Antimony Trichloride - Bis(1,2,4-triazolium) pentachloroantimonate(III)-1,2,4-triazolium Chloride

2002 ◽  
Vol 57 (2) ◽  
pp. 157-164 ◽  
Author(s):  
Maciej Bujak ◽  
Jacek Zaleski
Keyword(s):  
Hydrogen Bonds ◽  
Crystal And Molecular Structure ◽  
Antimony Trichloride ◽  
Organic Cations ◽  
Orthorhombic Space Group ◽  
Monoclinic System ◽  
Space Group ◽  
Anionic Sublattice ◽  
Cell Dimensions ◽  
Unit Cell Dimensions

The structures of 1,2,4-triazolium chloride (C2H4N3)Cl and its derivative with antimony trichloride - (C2H4N3)2[SbCl5] · (C2H4N3)Cl containing unsubstituted 1,2,4-triazolium cations were determined. (C2H4N3)Cl crystallizes in the monoclinic system, space group P21/n with the unit cell dimensions at 86 K: a = 9.425(2), b = 8.557(2), c = 11.158(2)Å , β = 95.87(3)°; V = 895.2(3)Å3, Z=8, dc = 1.566, dm = 1.56(2) g·cm-3.At roomtemperature, crystals of (C2H4N3)2- [SbCl5] · (C2H4N3)Cl are orthorhombic, space group P212121, a = 8.318(2), b = 11.381(2), c = 19.931(4) Å, V = 1886.8(7) Å3, Z = 4, dc = 1.917, dm = 1.91(2) g·cm-3. In both crystals the 1,2,4-triazole rings are planar. The anionic sublattice of (C2H4N3)2[SbCl5]·(C2H4N3)Cl consists of polymeric [SbCl5]n 2- zig-zag chains composed of distorted [SbCl6]3- octahedra connected via their vertices and the single Cl- anions. The cavities between the inorganic chains are filled by 1,2,4-triazolium cations. The nature of the distortion of the [SbCl6]3- polyhedra has been studied by examining correlations between the Sb-Cl bond lengths and the strength of hydrogen bonds, which join the anionic sublattice and the organic cations. This study confirms that the deformation of the [SbCl6]3- octahedra is caused by hydrogen bonds.

Unravelling Local Atomic Order of the Anionic Sublattice in M(Al1−xGax)4with M=Sr and Ba by Using NMR Spectroscopy and Quantum Mechanical Modelling

2016 ◽  
Vol 22 (49) ◽  
pp. 17833-17842 ◽  
Author(s):  
Oliver Pecher ◽  
Bernhard Mausolf ◽  
Volker Peters ◽  
Kevin Lamberts ◽  
Alexander Korthaus ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Quantum Mechanical ◽  
Atomic Order ◽  
Anionic Sublattice ◽  
Mechanical Modelling
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