Regioselective allylation and propargylation using acylsilanes: facile synthesis of PGE3 and F3α methyl ester

Tetrahedron ◽  
1992 ◽  
Vol 48 (11) ◽  
pp. 1969-1980 ◽  
Author(s):  
Akira Yanagisawa ◽  
Shigeki Habaue ◽  
Hisashi Yamamoto
1997 ◽  
Vol 1 (4) ◽  
pp. 259-263 ◽  
Author(s):  
Pēteris Trapencieris ◽  
Ivars Kalviņš ◽  
Larisa Kauliņa ◽  
Valerjans Kauss

Synthesis ◽  
2021 ◽  
Author(s):  
Narshinha Argade ◽  
santosh Vasantrao Shelar

A facile synthesis of methyl ester of chaetogline A is reported starting from the corresponding methyl 1-methyltryptophanate derived maleimide. A stereoselective Wittig olefination with a carbonyl function in methyl pyruvate followed by phosphorous pentoxide induced regioselective dehydrative cyclization are the essential reactions. An acid induced thermodynamically driven stereoselective β- to α-position migration of the exocyclic carbon−carbon double unit in ethyl tetrahydroindolizinoindolylidenepropanoate is described.


2019 ◽  
Vol 14 (8) ◽  
pp. 828-830 ◽  
Author(s):  
Weihua Meng ◽  
Weihong Wu ◽  
Weiwei Zhang ◽  
Luyao Cheng ◽  
Yunhong Jiao ◽  
...  

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