The kinetics of combustion of petroleum coke particles in a fluidized-bed combustor

1982 ◽  
Vol 19 (1) ◽  
pp. 1087-1092 ◽  
Author(s):  
R.D. LaNauze ◽  
K. Jung
Author(s):  
Jinsheng Wang ◽  
Edward J. Anthony ◽  
J. Carlos Abanades

Petroleum coke is regarded as a difficult fuel because of its high sulphur content and low volatile content. However, its low price and increased production, means that there is a powerful economic stimulus to use it for power generation. In this work, a process simulation has been performed as part of a feasibility study on the utilization of petroleum coke for power generation with low-cost CO2 capture. The proposed system employs a pressurized fluidized bed combustor and a calciner. In the combustor itself, the petroleum coke is burned and most of the CO2 generated is captured by a CaO sorbent under pressurized condition to form CaCO3. The CaCO3 is transported into the calciner where limited proportion of the petroleum coke is burned with pure O2, and calcines the spent sorbent back into CaO and CO2. A nearly pure CO2 stream is obtained from the calciner for subsequent disposal or utilization. The predicted overall efficiency of the combustion is near 40%. The proposed system would also be suitable for firing other high carbon and low ash fuel, such as anthracite.


2001 ◽  
Vol 15 (5) ◽  
pp. 1220-1224 ◽  
Author(s):  
Tadaaki Shimizu ◽  
Tomoyasu Fujikawa ◽  
Masaru Tonsho ◽  
Makoto Inagaki

2001 ◽  
Vol 80 (8) ◽  
pp. 758-764 ◽  
Author(s):  
Shinichi SAKUNO ◽  
Nobuhiro MISAWA ◽  
Nobuyuki SUZUKI ◽  
Hachiro UEDA ◽  
Hiroshi SASATSU ◽  
...  

1983 ◽  
Vol 52 ◽  
pp. 37-45 ◽  
Author(s):  
L.K. Chan ◽  
A.F. Sarofim ◽  
J.M. Beér

1993 ◽  
Vol 28 (2) ◽  
pp. 135-144 ◽  
Author(s):  
S. Matsui ◽  
R. Ikemoto Yamamoto ◽  
Y. Tsuchiya ◽  
B. Inanc

Using a fluidized bed reactor, experiments on glucose decomposition with and without sulfate reduction were conducted. Glucose in the reactor was mainly decomposed into lactate and ethanol. Lactate was mainly decomposed into propionate and acetate, while ethanol was decomposed into propionate, acetate, and hydrogen. Sulfate reduction was not involved in the decomposition of glucose, lactate, and ethanol, but was related to propionate and acetate decomposition. The stepwise reactions were modeled using either a Monod expression or first order reaction kinetics in respect to the reactions. The coefficients of the kinetic equations were determined experimentally. The modified Monod and first order reaction equations were effective at predicting concentrations of glucose, lactate, ethanol, propionate, acetate, and sulfate along the beight of the reactor. With sulfate reduction, propionate was decomposed into acetate, while without sulfate reduction, accumulation of propionate was observed in the reactor. Sulfate reduction accelerated propionate conversion into acetate by decreasing the hydrogen concentration.


1988 ◽  
Vol 56 (3) ◽  
pp. 157-163 ◽  
Author(s):  
J. Thýn ◽  
Z. Kolar ◽  
W. Martens ◽  
A. Korving

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