00/02647 Thermal and electrochemical studies of carbons for Li-ion batteries. 2. Correlation of active sites and irreversible capacity loss

2000 ◽  
Vol 41 (5) ◽  
pp. 295
2016 ◽  
Vol 4 (47) ◽  
pp. 18416-18425 ◽  
Author(s):  
Fu-Da Yu ◽  
Lan-Fang Que ◽  
Zhen-Bo Wang ◽  
Yin Zhang ◽  
Yuan Xue ◽  
...  

We report an effective approach to fabricate layered-spinel capped nanotube assembled 3D Li-rich hierarchitectures as a cathode material for Li-ion batteries. The resultant material exhibits a reduced first-cycle irreversible capacity loss, rapid Li-ion diffusion rate and excellent cycle stability.


1999 ◽  
Author(s):  
W. Jiang ◽  
X. Song ◽  
K. Kinoshita ◽  
T. Tran

2017 ◽  
Vol 164 (12) ◽  
pp. A2374-A2389 ◽  
Author(s):  
Bramy Pilipili Matadi ◽  
Sylvie Geniès ◽  
Arnaud Delaille ◽  
Claude Chabrol ◽  
Eric de Vito ◽  
...  

2015 ◽  
Vol 3 (42) ◽  
pp. 20935-20943 ◽  
Author(s):  
Sang-Hoon Park ◽  
Dongjoon Ahn ◽  
Young-Min Choi ◽  
Kwang Chul Roh ◽  
Kwang-Bum Kim

The low initial coulombic efficiency of a Si-based anode can hinder the performance of practical full-cell Li-ion batteries (LIBs), as the irreversible capacity loss of the anode can diminish the reversible full-cell capacity and the energy efficiency.


2018 ◽  
Vol 6 (28) ◽  
pp. 13883-13893 ◽  
Author(s):  
Yanying Liu ◽  
Zhe Yang ◽  
Jianling Li ◽  
Bangbang Niu ◽  
Kai Yang ◽  
...  

The modification of lithium-rich layered cathode materials has been widely studied by surface coating, doping and chemical treatment for lithium-ion batteries.


2020 ◽  
Vol 8 (17) ◽  
pp. 8540-8547 ◽  
Author(s):  
Chaoyu Hong ◽  
Qianyi Leng ◽  
Jianping Zhu ◽  
Shiyao Zheng ◽  
Huajin He ◽  
...  

Slow lithium diffusion kinetics of H1 phase during discharge determines the initial irreversible capacity loss of NCM-based materials. By controlling lithium diffusion rate in the discharge process, extra capacity is obtained in the materials.


2021 ◽  
Vol 894 ◽  
pp. 61-66
Author(s):  
Rui Zhi Dong

Due to the development of various mobile electronic devices, such as electric vehicles, rechargeable ion batteries are becoming more and more important. However, the current commercial lithium-ion batteries have obvious defects, including poor safety from Li dendrite and flammable electrolyte, quick capacity loss and low charging and discharging rate. It is very important to find a better two-dimensional material as the anode of the battery to recover the disadvantages. In this paper, first principles calculations are used to explore the performances of VS2 bilayer and VS2 / graphene heterostructure as the anodes of Li ion batteries. Based on the calculation of the valences, binding energy, intercalation voltage, charge transfer and diffusion barrier of Li, it is found that the latter can be used as a better anode material from the perspective of insertion voltage and binding energy. At the same time, the former one is better in terms of diffusion barrier. Our study provides a comprehensive understanding on VS2 based 2D anodes.


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