Colloidal and polymeric nature of fossil amber

1999 ◽  
Vol 30 (8) ◽  
pp. 971-983 ◽  
Author(s):  
Douglas Gold ◽  
Benjamin Hazen ◽  
Wilmer G. Miller
Keyword(s):  
2018 ◽  
Vol 131 (4) ◽  
pp. 1089-1094 ◽  
Author(s):  
Peyman Delparastan ◽  
Katerina G. Malollari ◽  
Haeshin Lee ◽  
Phillip B. Messersmith

Author(s):  
M. Calligaris ◽  
A. Ciana ◽  
S. Meriani ◽  
G. Nardin ◽  
L. Randaccio ◽  
...  
Keyword(s):  

IUCrData ◽  
2016 ◽  
Vol 1 (4) ◽  
Author(s):  
Sylvain Bernès ◽  
Laura Gasque

The structure of the title complex, [Pb(NO3)(C5H11NO2)2(H2O)2]NO3, had been determined previously at 173 and 193 K, and is now reported at 296 K, in the same space group. The main difference with the low-temperature structures is that a methyl group of one valine ligand is clearly disordered over two positions, for which the occupancies converged to 0.56 (3) and 0.44 (3). Bond-length variations within the coordination sphere of PbIIas a function ofTare difficult to assess because uncertainties on these parameters are high. On the other hand, Pb...O distances above 2.9 Å cannot be assigned unambiguously to formal Pb—O bonds. As a consequence, the polymeric nature of the complex previously described at 173 K is uncertain, as well as the actual coordination number of PbII, and it is thus not possible to determine if the metal environment is holo- or hemidirected.


1979 ◽  
Vol 34 (5) ◽  
pp. 625-630 ◽  
Author(s):  
O. K. Medhi ◽  
U. Agarwala

Abstract Some Europium(III) dibenzoylmethide and benzoylacetonate complexes have been subjected to Mössbauer studies at liquid nitrogen temperature. An attempt is made to discuss covalency in these complexes in terms of 6s, 4f and/or 5d orbital participation in the bond formation. Small linewidths are correlated to less symmetric structures. Resonance effects reflect the polymeric nature of these chelates.


1982 ◽  
Vol 24 (4) ◽  
pp. 952-963 ◽  
Author(s):  
A.Ye Chuchin ◽  
O.T Ivanilova

1970 ◽  
Vol 23 (10) ◽  
pp. 1963 ◽  
Author(s):  
EW Radoslovich ◽  
MR Raupach ◽  
PG Slade ◽  
RM Taylor

A series of crystalline metal glycerolato complexes has been prepared. The preparation of the cobalt, zinc, manganese, and iron complexes [(1 )-(4)] was achieved by heating (above 110�) glycerol with metal acetates, carbonates, oxalates, oxides, or hydroxides. The structure of (1) has been determined by X-rays and contains Co-O-Co-O and Co-O-C-C-O rings. X-ray powder diffraction and i.r. data are given for (1)-(4). These show (1) and (2) to be isostructural and that (3) and (4) are variants of these. The insolubility of (I), (2), (3), and (4) is in accord with their polymeric nature.


1955 ◽  
Vol 77 (22) ◽  
pp. 6080-6080 ◽  
Author(s):  
R. K. Summerbell ◽  
James R. Stephens
Keyword(s):  

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