Hydrophobic hydration of tert-butyl alcohol probed by NMR and IR

2000 ◽  
Vol 85 (1-2) ◽  
pp. 139-152 ◽  
Author(s):  
Kazuko Mizuno ◽  
Yuki Kimura ◽  
Hitomi Morichika ◽  
Yukari Nishimura ◽  
Shinji Shimada ◽  
...  
2011 ◽  
Vol 134 (5) ◽  
pp. 055104 ◽  
Author(s):  
L. Lupi ◽  
L. Comez ◽  
C. Masciovecchio ◽  
A. Morresi ◽  
M. Paolantoni ◽  
...  

2014 ◽  
Vol 119 (29) ◽  
pp. 9236-9243 ◽  
Author(s):  
L. Comez ◽  
M. Paolantoni ◽  
L. Lupi ◽  
P. Sassi ◽  
S. Corezzi ◽  
...  

1993 ◽  
Vol 58 (5) ◽  
pp. 1001-1006 ◽  
Author(s):  
Oľga Vollárová ◽  
Ján Benko

The kinetics of oxidation of [Co(en)2SCH2COO]+ with S2O82- was studied in water-methanol and water-tert-butyl alcohol mixtures. Changes in the reaction activation parameters ∆H≠ and ∆S≠ with varying concentration of the co-solvent depend on the kind of the latter, which points to a significant role of salvation effects. The solvation effect on the reaction is discussed based on a comparison of the transfer functions ∆Ht0, ∆St0 and ∆Gt0 for the initial and transition states with the changes in the activation parameters accompanying changes in the CO-solvent concentration. The transfer enthalpies of the reactant were obtained from calorimetric measurements.


2021 ◽  
pp. 116913
Author(s):  
Márcio José da Silva ◽  
Diego Morais Chaves ◽  
Sukarno Olavo ferreira ◽  
Rene Chagas da Silva ◽  
Jose Balena Gabriel Filho ◽  
...  

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