Synthesis, crystal structure and magnetic properties of a manganese(III) complex with bound water and double hydrogen-bonding bridges

Polyhedron ◽  
1997 ◽  
Vol 16 (8) ◽  
pp. 1273-1277 ◽  
Author(s):  
Xiang Shi Tan ◽  
Dao Feng Xiang ◽  
Wen Xia Tang ◽  
Min Qin Chen
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Hydrogen Bonding ◽  
Bound Water ◽  
Double Hydrogen

scholarly journals Zur Kenntnis von Be[C2(COO)2] · 4 H2O — Ein durch starke Wasserstoffbrückenbindungen stabilisiertes anorganisches Derivat der Acetylendicarbonsäure / On Be[C2(COO)2] · 4 H2O — An Inorganic Derivative of Acetylenedicarboxylic Acid Stabilized by Strong Hydrogen Bonding

1990 ◽  
Vol 45 (11) ◽  
pp. 1499-1502 ◽  
Author(s):  
Christian Robl ◽  
Stephanie Hentschel
Keyword(s):  
Crystal Structure ◽  
Thermal Decomposition ◽  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Single Crystals ◽  
Three Dimensional ◽  
Bound Water ◽  
Water Molecules ◽  
Acetylenedicarboxylic Acid ◽  
Hydrogen Bound

Colorless orthorhombic single crystals of Be[C2(COO)2] · 4 H2O were grown in aqueous silica gel. Space group Cmcm, α = 1004.7(1), b = 675.0(1), c = 1262.4(2) pm, Rg = 0.0264. The crystal structure consists of Be(H2O)42+ tetrahedra and planar [C2(COO)2]2- anions linked together by strong asymmetric hydrogen bonds. A layer-like arrangement extending parallel (010) made up by [C2(COO)2]2- anions and hydrogen bound water molecules of the Be(H2O)42+ tetrahedra is the primary structural feature of Be[C2(COO)2] · 4H2O. These layers are stacked and interlinked by coordinative bonds between Be2+ and H2O to yield a rigid three-dimensional framework. Thermal decomposition commences with endothermic loss of water of crystallisation at 160 °C followed by several steps of exothermic degradation yielding finally a soot-like amorphous residue.

A neutron diffraction study of hydrogen bonding in the deuterium (hydrogen) L-arginine phosphate monohydrate

1997 ◽  
Vol 212 (3) ◽  
Author(s):  
Z. Cheng ◽  
Y. Cheng ◽  
L. Guo ◽  
D. Xu
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Neutron Diffraction ◽  
Diffraction Study ◽  
Title Compound ◽  
Neutron Diffraction Study ◽  
Chemical Formula

AbstractThe crystal structure of the title compound D(H)LAP with chemical formula (D

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