Role of lanthanide elements on the catalytic behavior of supported Pd catalysts in the reduction of NO with methane

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The catalytic selective reduction of NOxwith CO over Pd/Al2O3and Pd/TiO2/Al2O3under lean conditions (called SCR-deNOxin simple way) was studied here. The performance of the catalysts with different Pd loadings for deNOxwas investigated. The results showed that the 2.0 wt.% Pd/TiO2/Al2O3and 1.5 wt.% Pd/Al2O3catalysts displayed optimum deNOxactivities of 46% and 20% at 200°C, respectively. TEM, XRD, XPS and SEM were utilized to characterize the catalysts. Metallic palladium is thought to be the active site which highly dispersed on the catalyst supports. The synergy between TiO2and Al2O3or Pd is thought to be the reason for the obvious improvement in deNOxprocess.


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