The structure of high-performance polymer blends by small-angle neutron scattering

1997 ◽  
Vol 234-236 ◽  
pp. 240-241 ◽  
Author(s):  
J. Caspar ◽  
B. Dünges ◽  
R.G. Kirste ◽  
T. Heitz ◽  
A. Wiedenmann
1995 ◽  
Vol 16 (10) ◽  
pp. 771-778 ◽  
Author(s):  
Jörg Caspar ◽  
Bastian Dünges ◽  
Rudolf G. Kirste ◽  
Thomas Heitz ◽  
Albrecht Wiedenmann

1989 ◽  
Vol 166 ◽  
Author(s):  
Alan I. Nakatani ◽  
Hongdoo Kim ◽  
Charles C. Han

ABSTRACTThe phase behavior of polymer blends and solutions can be changed dramatically by a flow field using a variety of flow geometries. Unlike simple binary fluids which require extremely high shear rates to produce only small shifts in the phase boundary, polymer phase behavior may be influenced by as much as 10 degrees with the application of much lower shear rates. However, there is a large body of conflicting data concerning the nature of these shear effects in polymers.Here we report on the effects of shear on the phase behavior of polymer blends by small angle neutron scattering (SANS). Experiments were conducted using a specially constructed, concentric cylinder apparatus for in situ studies of concentrated polymer solutions and melts. Two separate systems will be discussed: 1) a blend of polystyrene and polybutadiene. 2) a blend of polystyrene and poly(vinylmethylether). Both systems exhibit shifts in the phase behavior which indicate shear induced mixing in agreement with previous results obtained by other techniques. These results will be interpreted within the context of existing theories of shear induced phase behavior.


2008 ◽  
Vol 41 (2) ◽  
pp. 471-477 ◽  
Author(s):  
Nisita S. Wanakule ◽  
Alisyn J. Nedoma ◽  
Megan L. Robertson ◽  
Zhuangxi Fang ◽  
Andrew Jackson ◽  
...  

2021 ◽  
pp. 1-5
Author(s):  
Huarui Wu ◽  
Weihang Hong ◽  
Yao Zhang ◽  
Pulin Bai ◽  
Wenbo Mo ◽  
...  

Developing small-angle neutron scattering techniques at compact accelerator-driven neutron sources (CANS) is of great importance for expanding the user community and advancing CANS capability. At the Compact Pulsed Hadron Source (CPHS) at Tsinghua University, neutron-focusing mirrors are under intensive research to address the challenge. A grazing-incidence focusing SANS (gif-SANS) project is initialized. It employs a nested supermirror assembly with a large collecting area to achieve ⩾ 10 5 n/s neutron intensity at Q min ⩽ 0.007 Å − 1 . It will equip two detectors, one being a 3He detector for normal Q-range measurements, and the other being a high-resolution detector for extending the Q min down to 10 − 3 Å − 1 . In this work, we present the conceptual design of the gif-SANS at CPHS. Such a scheme is conducive to enable high-performance SANS measurements at CANS.


1997 ◽  
Vol 30 (11) ◽  
pp. 3363-3368 ◽  
Author(s):  
Glenn C. Reichart ◽  
William W. Graessley ◽  
Richard A. Register ◽  
Ramanan Krishnamoorti ◽  
David J. Lohse

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