Vibrational circular dichroism, absolute configuration and predominant conformations of volatile anesthetics: 1,2,2,2-tetrafluoroethyl methyl ether

1999 ◽  
Vol 10 (6) ◽  
pp. 1099-1106 ◽  
Author(s):  
Prasad L Polavarapu ◽  
Chunxia Zhao ◽  
Keith Ramig
Keyword(s):  
Circular Dichroism ◽  
Methyl Ether ◽  
Absolute Configuration ◽  
Volatile Anesthetics ◽  
Vibrational Circular Dichroism ◽  
Circular Dichroïsm

Absolute Configuration of the Meroditerpenoids Taondiol and Epitaondiol Diacetates by Vibrational Circular Dichroism

Heterocycles ◽  
2012 ◽  
Vol 85 (8) ◽  
pp. 1961 ◽  
Author(s):  
Pedro Joseph-Nathan ◽  
Marcelo A. Muñoz ◽  
Carlos Areche ◽  
Juana Rovirosa ◽  
Aurelio San Martín ◽  
...  
Keyword(s):  
Circular Dichroism ◽  
Absolute Configuration ◽  
Vibrational Circular Dichroism ◽  
Circular Dichroïsm

Absolute Configuration of Sargaol Acetate Using DFT Calculations and Vibrational Circular Dichroism

Heterocycles ◽  
2010 ◽  
Vol 81 (3) ◽  
pp. 625 ◽  
Author(s):  
Pedro Joseph-Nathan ◽  
Marcelo A. Muñoz ◽  
Carlos Areche ◽  
Juana Rovirosa ◽  
Aurelio San-Martín
Keyword(s):  
Circular Dichroism ◽  
Dft Calculations ◽  
Absolute Configuration ◽  
Vibrational Circular Dichroism ◽  
Circular Dichroïsm

scholarly journals Piscicartone, a Rotenoid From Piscidia carthagenensis

2019 ◽  
Vol 14 (5) ◽  
pp. 1934578X1984979
Author(s):  
Alfredo R. Ortega ◽  
Nury Pérez-Hernández ◽  
Pedro Joseph-Nathan
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Fourier Transform ◽  
Circular Dichroism ◽  
Magnetic Resonance ◽  
Discrete Fourier Transform ◽  
Absolute Configuration ◽  
Vibrational Circular Dichroism ◽  
Magnetic Resonance Studies ◽  
Circular Dichroïsm ◽  
Nuclear Magnetic

The bark of the roots of Piscidia carthagenensis afforded the known insecticides rotenone (1) and millettone (2), as well as the new rotenoid piscicartone (3). The structure of 3 followed from nuclear magnetic resonance studies, while its absolute configuration (AC) was determined by vibrational circular dichroism (VCD) measurements in comparison with discrete Fourier transform B3LYP/DGDZVPcalculated spectra using the Compare VOA software. In addition, the AC of 1 and 2 was verified using the same VCD methodology.

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