Ring-opening metathesis polymerization (ROMP) of isomerically pure functional monomers and acyclic diene metathesis depolymerization (retro-ADMET) of functionalized polyalkenamers

2002 ◽  
Vol 190 (1-2) ◽  
pp. 117-129 ◽  
Author(s):  
Vincent Lapinte ◽  
Laurent Fontaine ◽  
Véronique Montembault ◽  
Irène Campistron ◽  
Danièle Reyx
Keyword(s):  
Ring Opening ◽  
Acyclic Diene Metathesis ◽  
Ring Opening Metathesis Polymerization ◽  
Functional Monomers ◽  
Metathesis Polymerization ◽  
Diene Metathesis

Polyethylene telechelics with POSS termini: synthesis, morphologies and shape memory properties

2020 ◽  
Vol 11 (36) ◽  
pp. 5819-5832
Author(s):  
Bingjie Zhao ◽  
Honggang Mei ◽  
Sixun Zheng
Keyword(s):  
Shape Memory ◽  
Ring Opening ◽  
Polyhedral Oligomeric Silsesquioxane ◽  
Acyclic Diene Metathesis ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization ◽  
Shape Memory Properties ◽  
Hydrogenation Reactions ◽  
Diene Metathesis ◽  
Oligomeric Silsesquioxane

Organic–inorganic polyethylene (PE) telechelics with polyhedral oligomeric silsesquioxane termini were synthesized via the combination of acyclic diene metathesis, ring-opening metathesis polymerization and hydrogenation reactions.

scholarly journals Application of olefin metathesis in the synthesis of functionalized polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials

2019 ◽  
Vol 15 ◽  
pp. 310-332 ◽  
Author(s):  
Patrycja Żak ◽  
Cezary Pietraszuk
Keyword(s):  
Olefin Metathesis ◽  
Ring Opening ◽  
Polymeric Materials ◽  
Acyclic Diene Metathesis ◽  
Polyhedral Oligomeric Silsesquioxanes ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization ◽  
Cross Metathesis ◽  
Terminal Olefins ◽  
Synthesized Materials

This mini-review summarizes the applications of olefin metathesis in synthesis and functionalization of polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials. Three types of processes, i.e., cross metathesis (CM) of vinyl-substituted POSS with terminal olefins, acyclic diene metathesis (ADMET) copolymerization of divinyl-substituted POSS with α,ω-dienes and ring-opening metathesis polymerization (ROMP) of POSS-substituted norbornene (or other ROMP susceptible cycloolefins) are discussed. Emphasis was put on the synthetic and catalytic aspects rather than on the properties and applications of synthesized materials.

Synthesis and Purification of Tunable High Tg Electro-Optical Polymers by Ring Opening Metathesis Polymerization

2011 ◽  
Author(s):  
Robert H. Lambeth ◽  
Joseph M. Dougherty ◽  
Joshua A. Orlicki ◽  
Adam M. Rawlett ◽  
Robert C. Hoffman ◽  
...  
Keyword(s):  
Ring Opening ◽  
Optical Polymers ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization
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