scholarly journals Morphology effect of zirconia support on the catalytic performance of supported Ni catalysts for dry reforming of methane

2016 ◽  
Vol 37 (12) ◽  
pp. 2122-2133 ◽  
Author(s):  
Weizuo Li ◽  
Zhongkui Zhao ◽  
Yanhua Jiao ◽  
Guiru Wang
2013 ◽  
Vol 34 (4) ◽  
pp. 764-768 ◽  
Author(s):  
Anis H FAKEEHA ◽  
Wasim U. KHAN ◽  
Ahmed S. AL-FATESH ◽  
Ahmed E. ABASAEED

2021 ◽  
Vol 23 (1) ◽  
pp. 617-627
Author(s):  
Yan Zhang ◽  
Yi-Fan Yao ◽  
Yuan-Yuan Qiao ◽  
Gui-Chang Wang

The entire reaction mechanism of the dry reforming of methane (DRM) as well as the competition processes over perfect and boron-vacancy-containing h-BN sheet-supported Ni-catalysts (labeled Ni2/h-BN and Ni2/h-BN-B–D) was studied by density functional theory calculations in the present work.


Chemistry ◽  
2018 ◽  
Vol 1 (1) ◽  
pp. 3-16 ◽  
Author(s):  
Cameron Price ◽  
Emily Earles ◽  
Laura Pastor-Pérez ◽  
Jian Liu ◽  
Tomas Reina

Encapsulation of metal nanoparticles is a leading technique used to inhibit the main deactivation mechanisms in dry reforming of methane reaction (DRM): Carbon formation and Sintering. Ni catalysts (15%) supported on alumina (Al2O3) and ceria (CeO2) have shown they are no exception to this analysis. The alumina supported catalysts experienced graphitic carbonaceous deposits, whilst the ceria showed considerable sintering over 15 h of DRM reaction. The effect of encapsulation compared to that of the performance of uncoated catalysts for DRM reaction has been examined at different temperatures, before conducting longer stability tests. The encapsulation of Ni/ZnO cores in silica (SiO2) leads to advantageous conversion of both CO2 and CH4 at high temperatures compared to its uncoated alternatives. This work showcases the significance of the encapsulation process and its overall effects on the catalytic performance in chemical CO2 recycling via DRM.


Sign in / Sign up

Export Citation Format

Share Document