HREM study of crystal-amorphous transformation of Cu-Ti multilayers by cold-rolling

Author(s):  
W. A. Chiou ◽  
C. S. Lin ◽  
M. Meshii

Amorphous alloys have been of scientific interest for more than three decades because of their improved properties (physical, mechanical, magnetic, corrosion, etc.) as compared with those of the same alloys in the crystalline states. Recently, solid-state reactions have been shown to be a potential technology for synthesis of amorphous metallic alloys. While different mechanisms of amorphization have been proposed, the real process is still in debate. To study the amorphization process in more detail, information of structural transformation from crystalline to amorphous states during the processing (e.g., mechanical alloying) is essential. This paper presents an interfacial study of Cu and Ti foils by cold-rolling.

Author(s):  
W. A. Chiou ◽  
N. L. Jeon ◽  
Genbao Xu ◽  
M. Meshii

For many years amorphous metallic alloys have been prepared by rapid quenching techniques such as vapor condensation or melt quenching. Recently, solid-state reactions have shown to be an alternative for synthesizing amorphous metallic alloys. While solid-state amorphization by ball milling and high energy particle irradiation have been investigated extensively, the growth of amorphous phase by cold-rolling has been limited. This paper presents a morphological and structural study of amorphization of Cu and Ti foils by rolling.Samples of high purity Cu (99.999%) and Ti (99.99%) foils with a thickness of 0.025 mm were used as starting materials. These thin foils were cut to 5 cm (w) × 10 cm (1), and the surface was cleaned with acetone. A total of twenty alternatively stacked Cu and Ti foils were then rolled. Composite layers following each rolling pass were cleaned with acetone, cut into half and stacked together, and then rolled again.


1998 ◽  
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pp. 151-156 ◽  
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C.A. Nannetti ◽  
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Marcel Miglierini

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