Indirect Determination of Inorganic Phosphate by Atomic Absorption Spectrophotometric Determination of Molybdenum.

1966 ◽  
Vol 38 (12) ◽  
pp. 1759-1760 ◽  
Author(s):  
W. S. Zaugg ◽  
R. J. Knox
1994 ◽  
Vol 59 (10) ◽  
pp. 2227-2234 ◽  
Author(s):  
Václav Stužka ◽  
Jaromír Souček

A new method has been developed for the indirect determination of nitroso- and nitrophenols by atomic absorption spectrometry (AAS) after extraction of ionic associates involving bipyridylocopper(II) (CuDP) or phenanthrolinocopper(II) (CuPH) complexes. Nitrobenzene and methyl isobutyl ketone appeared to be suitable for the extraction. It was possible to determine several tenths to hundredths of a milligram of nitrophenol in a litre. Extractable associates with CuDP and CuPH are formed by phenols possessing two substituents or by higher molecular weight phenols such as naphthol or hydroxyquinoline. Monosubstituted phenols fail to form associates of this kind.


1974 ◽  
Vol 7 (12) ◽  
pp. 627-635
Author(s):  
A. Radecki ◽  
H. Lamparczyk ◽  
J. Grzybowski ◽  
J. Halkiewicz

1979 ◽  
Vol 62 (1) ◽  
pp. 153-159
Author(s):  
Luis F Corominas ◽  
Victor M Boy ◽  
Manuel Guijosa

Abstract The official first action AOAC method for the spectrophotometric determination of biuret in urea, 2.072—2.074, was compared with official first action AOAC method 2.C01-2.C03 (atomic absorption spectrophotometry), 2 simplified versions of 2.072-2.074, and modified versions of 2 alternative procedures of the International Organization for Standardization. Three synthetic urea samples (0.3, 1.4, and 3.0% biuret) and 1 commercial urea sample (1.0% biuret) were analyzed. The methods proved to be equivalent and none showed a definite advantage over 2.072-2.074. The purification of biuret and the interference by ammonia are also discussed.


The Analyst ◽  
1984 ◽  
Vol 109 (2) ◽  
pp. 123-125 ◽  
Author(s):  
José Aznárez ◽  
Francisco Palacios ◽  
Maria S. Ortega ◽  
Juan Carlos Vidal

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