Mechanism of the Novel Prenylated Flavin-Containing Enzyme Ferulic Acid Decarboxylase Probed by Isotope Effects and Linear Free-Energy Relationships

Biochemistry ◽  
2016 ◽  
Vol 55 (20) ◽  
pp. 2857-2863 ◽  
Author(s):  
Kyle L. Ferguson ◽  
Nattapol Arunrattanamook ◽  
E. Neil G. Marsh
Keyword(s):  
Free Energy ◽  
Ferulic Acid ◽  
Isotope Effects ◽  
Acid Decarboxylase ◽  
The Novel ◽  
Linear Free Energy Relationships ◽  
Linear Free Energy ◽  
Ferulic Acid Decarboxylase ◽  
Energy Relationships

scholarly journals Mechanistic Insights into RNA Transphosphorylation from Kinetic Isotope Effects and Linear Free Energy Relationships of Model Reactions

2014 ◽  
Vol 20 (44) ◽  
pp. 14336-14343 ◽  
Author(s):  
Haoyuan Chen ◽  
Timothy J. Giese ◽  
Ming Huang ◽  
Kin-Yiu Wong ◽  
Michael E. Harris ◽  
...  
Keyword(s):  
Free Energy ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Linear Free Energy Relationships ◽  
Linear Free Energy ◽  
Kinetic Isotope ◽  
Energy Relationships ◽  
Model Reactions

On the displacement reactions of organic substances in water

2005 ◽  
Vol 83 (9) ◽  
pp. 1667-1719 ◽  
Author(s):  
J MW Scott
Keyword(s):  
Free Energy ◽  
Temperature Dependence ◽  
Isotope Effects ◽  
Linear Free Energy Relationship ◽  
Linear Free Energy Relationships ◽  
Organic Substances ◽  
Linear Free Energy ◽  
Organic Halides ◽  
Displacement Reactions ◽  
Energy Relationships

The hydrolyses of a series of organic halides, nitrates, sulphonates, and perchlorates are examined from the standpoint of thermodynamics, kinetics, temperature dependence, isotope effects, the Kurz equation, and the Guthrie linear free energy relationship. The thermodynamics of several definite bimolecular displacements are also examined. Some mechanistic revisions are suggested to reach an improved accommodation with the experimental observations.Key words: kinetics, thermodynamics, hydrolytic displacements, mechanism, ionic displacements, nucleofugality, linear free energy relationships.

Linear free energy relationships in CN bond dissociations in molecular ions of 4-substitutedN-(2-furylmethyl)anilines in the gas phase

2007 ◽  
Vol 42 (11) ◽  
pp. 1496-1503 ◽  
Author(s):  
Eduardo A. Solano Espinoza ◽  
Elena Stashenko ◽  
Jairo Martínez ◽  
Uriel Mora ◽  
Vladimir Kouznetsov
Keyword(s):  
Free Energy ◽  
Gas Phase ◽  
Molecular Ions ◽  
Linear Free Energy Relationships ◽  
Linear Free Energy ◽  
Energy Relationships

Linear Free Energy Relationships in the Intrinsic and GTPase Activating Protein-Stimulated Guanosine 5‘-Triphosphate Hydrolysis of p21ras†

Biochemistry ◽  
1996 ◽  
Vol 35 (45) ◽  
pp. 14225-14231 ◽  
Author(s):  
T. Schweins ◽  
M. Geyer ◽  
H. R. Kalbitzer ◽  
A. Wittinghofer ◽  
A. Warshel
Keyword(s):  
Free Energy ◽  
Linear Free Energy Relationships ◽  
Gtpase Activating Protein ◽  
Linear Free Energy ◽  
Energy Relationships ◽  
Hydrolysis Of
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