Native Vanadyl Complexes in Crude Oil as Polarizing Agents for In Situ Proton Dynamic Nuclear Polarization

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Polymerization reactions of the dissolved gases propene, 1-butene, and isobutene catalyzed by [Zr(Cp)2Me][B(C6F5)4] were characterized using in-situ NMR. Hyperpolarization of 13C spins by the dissolution dynamic nuclear polarization (DNP) technique...


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High-field Dynamic Nuclear Polarization is a powerful tool for the structural characterization of species on the surface of porous materials or nanoparticles. For these studies the main source of polarization...


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