The spatiotemporal locations of large populations are difficult to clearly characterize using traditional exposure assessment, mainly due to their complicated daily intraurban activities. This study aimed to extract hourly locations for the total population of Beijing based on cell phone data and assess their dynamic exposure to ambient PM2.5. The locations of residents were located by the cellular base stations that were keeping in contact with their cell phones. The diurnal activity pattern of the total population was investigated through the dynamic spatial distribution of all of the cell phones. The outdoor PM2.5 concentration was predicted in detail using a land use regression (LUR) model. The hourly PM2.5 map was overlapped with the hourly distribution of people for dynamic PM2.5 exposure estimation. For the mobile-derived total population, the mean level of PM2.5 exposure was 89.5 μg/m3 during the period from 2013 to 2015, which was higher than that reported for the census population (87.9 μg/m3). The hourly activity pattern showed that more than 10% of the total population commuted into the center of Beijing (e.g., the 5th ring road) during the daytime. On average, the PM2.5 concentration at workplaces was generally higher than in residential areas. The dynamic PM2.5 exposure pattern also varied with seasons. This study exhibited the strengths of mobile location in deriving the daily spatiotemporal activity patterns of the population in a megacity. This technology would refine future exposure assessment, including either small group cohort studies or city-level large population assessments.
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