Validation and Application of a 3-Step Sequential Extraction Method to Investigate the Fraction Transformation of Organic Pollutants in Aging Soils: A Case Study of Dechlorane Plus

2018 ◽  
Vol 53 (3) ◽  
pp. 1325-1333 ◽  
Author(s):  
Yu Cheng ◽  
Jue Ding ◽  
Xianchuan Xie ◽  
Xiaowen Ji ◽  
Youkuan Zhang
2001 ◽  
Vol 35 (13) ◽  
pp. 2778-2784 ◽  
Author(s):  
N. E. Keon ◽  
C. H. Swartz ◽  
D. J. Brabander ◽  
C. Harvey ◽  
H. F. Hemond

2015 ◽  
Vol 20 (6) ◽  
pp. 111-116 ◽  
Author(s):  
Gyeonghye Moon ◽  
Hongki Park ◽  
Kyoungkeun Yoo ◽  
Jha Manis Kumar ◽  
Alorro Richad Diaz ◽  
...  

Author(s):  
Andrea Lazo ◽  
Henrik Hansen ◽  
Pamela Lazo ◽  
Claudia Gutiérrez

Mine tailings have been analyzed by a sequential extraction procedure after their pre-treatment with a leaching solution for 24 h and electrodialytic remediation during 15 days with a constant electric field of 2.7 V cm−1. Four leaching solutions were tested: H2SO4 + HNO3 (2:1 vol.) pH = 1.9; H2SO4 + HNO3 (2:1 vol) pH = 4.2; NH4Cl 0.8M, pH = 5.5 and 30% H2O2 adjusted to pH 2 with HNO3 1M + HCl 1M. After the treatment, the tailings were divided in six slices from anode to cathode. The highest removal efficiency of copper was obtained with H2SO4 + HNO3 pH = 1.9, which allows one to remove 67% of the copper in the total cell and 85% of the copper in the slice closest to anode. The same solution with pH = 4.2 allows one to remove 62% of the total copper. The analysis realized by the sequential extraction method indicates the easy removal of water-soluble and exchangeable fractions in all experiments, moreover, residual and sulfide are the less mobile fractions. The general trend was the movement of copper associated to different fractions from anode to cathode and its accumulation closest to the cathode in the case of exchangeable, Fe-Mn oxides and acid soluble fractions, possibly due to some precipitation of copper compounds associated with less acidic conditions.


2014 ◽  
Vol 1010-1012 ◽  
pp. 452-455
Author(s):  
Zhe Hu ◽  
Ke Feng Zhang ◽  
Lei Liu

By the chemical sequential extraction method, various chemical speciation of phosphorus were extracted from shallow sediments of Nansi Lake. Aiming at the existing problems of lower concentration of phosphorus, the method combined the original sequential extraction and Mo-Sb Anti spectrophotometric method was improved to reduce the interference caused by stratification and chromogenic reaction. In addition, due to the presence of excess sodium dithionite, the extracting solution need to be diluted during occlude phosphorus (Oc-P) extraction process.


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