Stabilized Cu2O Nanoparticles on Macroporous Polystyrene Resins [Cu2O@ARF]: Improved and Reusable Heterogeneous Catalyst for On-Water Synthesis of Triazoles via Click Reaction

A new protocol has been developed for the photoinduced CuAAC click reaction using heterogeneous mesoporous graphitic carbon nitride as the photocatalyst.

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Graphene-supported Cu2O nanoparticles: an efficient heterogeneous catalyst for C–O cross-coupling of aryl iodides with phenols

Catalysis Science & Technology ◽

10.1039/c4cy01048e ◽

2014 ◽

Vol 4 (12) ◽

pp. 4196-4199 ◽

Cited By ~ 21

Author(s):

Zhaoyang Zhai ◽

Xiaoning Guo ◽

Zhifeng Jiao ◽

Guoqiang Jin ◽

Xiang-Yun Guo

Keyword(s):

Heterogeneous Catalyst ◽

Cross Coupling ◽

Aryl Iodides ◽

Cu2o Nanoparticles ◽

Efficient Heterogeneous Catalyst

Cu2O/graphene as a heterogeneous catalyst can efficiently catalyze the C–O cross-coupling of aryl iodides with phenols.

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Preparation and characterization of a novel spherical cellulose–copper(II) oxide composite particles: as a heterogeneous catalyst for the click reaction

Molecular Diversity ◽

10.1007/s11030-019-09942-7 ◽

2019 ◽

Vol 24 (1) ◽

pp. 201-209 ◽

Cited By ~ 4

Author(s):

Seyedeh Fazileh Hamzavi ◽

Sanaz Gerivani ◽

Simin Saeedi ◽

Kobra Naghdipari ◽

Gholamhossein Shahverdizadeh

Keyword(s):

Heterogeneous Catalyst ◽

Click Reaction ◽

Composite Particles ◽

Oxide Composite

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Stabilized Cu/Cu2O nanoparticles on rGO as an efficient heterogeneous catalyst for Glaser homo-coupling

Catalysis Communications ◽

10.1016/j.catcom.2019.04.002 ◽

2019 ◽

Vol 125 ◽

pp. 98-102 ◽

Cited By ~ 6

Author(s):

Weiyang Lu ◽

Wei Sun ◽

Xiaofeng Tan ◽

Lingfeng Gao ◽

Gengxiu Zheng

Keyword(s):

Heterogeneous Catalyst ◽

Cu2o Nanoparticles ◽

Efficient Heterogeneous Catalyst

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Cu/Cu2O Nanoparticles Supported on a Phenol–Pyridyl COF as a Heterogeneous Catalyst for the Synthesis of Unsymmetrical Diynes via Glaser–Hay Coupling

ACS Applied Materials & Interfaces ◽

10.1021/acsami.9b02860 ◽

2019 ◽

Vol 11 (17) ◽

pp. 15670-15679 ◽

Cited By ~ 28

Author(s):

Debanjan Chakraborty ◽

Shyamapada Nandi ◽

Dinesh Mullangi ◽

Sattwick Haldar ◽

Chathakudath P. Vinod ◽

...

Keyword(s):

Heterogeneous Catalyst ◽

Cu2o Nanoparticles

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Preparation and characterization of TiO2-nanotube/Ti plates loaded Cu2O nanoparticles as a novel heterogeneous catalyst for the azide–alkyne cycloaddition

Catalysis Communications ◽

10.1016/j.catcom.2016.01.002 ◽

2016 ◽

Vol 76 ◽

pp. 72-75 ◽

Cited By ~ 22

Author(s):

Masoud Faraji ◽

Mojtaba Amini ◽

Alireza Pourvahabi Anbari

Keyword(s):

Heterogeneous Catalyst ◽

Tio2 Nanotube ◽

Cu2o Nanoparticles

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Triazolium-Containing Metal–Organic Frameworks: Control of Catenation in 2D Copper(II) Paddlewheel Structures

Australian Journal of Chemistry ◽

10.1071/ch12462 ◽

2013 ◽

Vol 66 (4) ◽

pp. 409 ◽

Cited By ~ 6

Author(s):

Alexandre Burgun ◽

Christian J. Doonan ◽

Christopher J. Sumby

Keyword(s):

Benzoic Acid ◽

Heterogeneous Catalyst ◽

Click Reaction ◽

Metal Organic Frameworks ◽

Ester Hydrolysis ◽

Charge Balance ◽

Reaction Conditions ◽

Metal Organic ◽

Methyl Triflate

One approach to exploit metal–organic frameworks (MOFs) as heterogeneous catalyst platforms requires the development of materials containing groups that can be utilised to anchor a catalytic moiety into the links within the structure. Here we report the synthesis of the first integrated triazolium-containing MOF linker and the first MOFs containing linkers of this type. 1,4-Bis(4-benzoic acid)-1-methyl-1H-1,2,3-triazolium chloride, H2L1Me, was synthesised in three steps by a ‘click’ reaction of methyl 4-ethynylbenzoate with methyl 4-azidobenzoate, methylation using methyl triflate, followed by ester hydrolysis in overall 74 % yield. The equivalent neutral triazole precursor, 1,4-bis(4-benzoic acid)-1H-1,2,3-triazole hydrochloride, H2L1(HCl), was also prepared and a comparison of the chemistry with Zn(NO3)2·6H2O and Cu(NO3)2·3H2O is presented. The results support the use of reaction conditions to control interpenetration and provide additional evidence that the charge on structurally similar ligands can drastically alter the types of structures that are accessible due to the requirements for charge balance in the final product.

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