Trivalent Actinide Ions Showing Tenfold Coordination in Solution

2020 ◽  
Vol 59 (17) ◽  
pp. 12410-12421
Author(s):  
Patrik Weßling ◽  
Tobias Schenk ◽  
Felix Braun ◽  
Björn B. Beele ◽  
Sascha Trumm ◽  
...  
Keyword(s):  
Actinide Ions ◽  
Trivalent Actinide

Complexing of trivalent actinide ions by thiocyanate

1974 ◽  
Vol 36 (5) ◽  
pp. 1131-1134 ◽  
Author(s):  
W.F. Kinard ◽  
G.R. Choppin
Keyword(s):  
Actinide Ions ◽  
Trivalent Actinide

Complexing of trivalent actinide ions by glycolate

1972 ◽  
Vol 34 (11) ◽  
pp. 3473-3477 ◽  
Author(s):  
G.R. Choppin ◽  
G. Degischer
Keyword(s):  
Actinide Ions ◽  
Trivalent Actinide

The acetate complexing by trivalent actinide ions

1970 ◽  
Vol 32 (10) ◽  
pp. 3283-3288 ◽  
Author(s):  
Gregory R. Choppin ◽  
Joan K. Schneider
Keyword(s):  
Actinide Ions ◽  
Trivalent Actinide

Semi-empirical Calculations on the Free Energy and Enthalpy of Hydration for the Trivalent Lanthanides and Actinides

1975 ◽  
Vol 53 (18) ◽  
pp. 2695-2700 ◽  
Author(s):  
Saul Goldman ◽  
Lester R. Morss
Keyword(s):  
Free Energy ◽  
Noble Gas ◽  
Hydration Number ◽  
Enthalpy Of Hydration ◽  
Trivalent Lanthanides ◽  
Experimental Enthalpy ◽  
Hydration Model ◽  
Actinide Ions ◽  
Trivalent Actinide ◽  
Enthalpy Data

An electrostatic hydration model, that had previously been developed for ions of the noble–gas structure, was applied to the trivalent lanthanide and trivalent actinide ions. For the trivalent lanthanides it was found that a single primary hydration number resulted in a satisfactory fit of the model to the experimental free energy and enthalpy data. Subsequently, the model was applied to the trivalent actinide ions with a view to predicting values for the free energy and enthalpy of hydration for this series. A primary hydration number for the actinide series was determined by fitting the model to existing experimental enthalpy data for Pu3+. The predictions for this series were found to compare favorably with the few experimental and estimated values that exist.

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