Electrochemical Properties and CO2-Reduction Ability of m-Terphenyl Isocyanide Supported Manganese Tricarbonyl Complexes

2016 ◽  
Vol 55 (23) ◽  
pp. 12400-12408 ◽  
Author(s):  
Douglas W. Agnew ◽  
Matthew D. Sampson ◽  
Curtis E. Moore ◽  
Arnold L. Rheingold ◽  
Clifford P. Kubiak ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Co2 Reduction ◽  
Manganese Tricarbonyl

scholarly journals An Investigation of Electrocatalytic CO2 Reduction Using a Manganese Tricarbonyl Biquinoline Complex

2019 ◽  
Vol 7 ◽  
Author(s):  
Meaghan McKinnon ◽  
Veronika Belkina ◽  
Ken T. Ngo ◽  
Mehmed Z. Ertem ◽  
David C. Grills ◽  
...  
Keyword(s):  
Co2 Reduction ◽  
Manganese Tricarbonyl

scholarly journals Effect of Redox Active Ligands on the Electrochemical Properties of Manganese Tricarbonyl Complexes

2019 ◽  
Vol 58 (11) ◽  
pp. 7453-7465 ◽  
Author(s):  
Benjamin D. Matson ◽  
Elizabeth A. McLoughlin ◽  
Keith C. Armstrong ◽  
Robert M. Waymouth ◽  
Ritimukta Sarangi
Keyword(s):  
Electrochemical Properties ◽  
Redox Active Ligands ◽  
Redox Active ◽  
Manganese Tricarbonyl

Ambiguous electrocatalytic CO2 reduction behaviour of a nickel bis(aldimino)pyridine pincer complex

2016 ◽  
Vol 45 (39) ◽  
pp. 15285-15289 ◽  
Author(s):  
Remya Narayanan ◽  
Meaghan McKinnon ◽  
Blake R. Reed ◽  
Ken T. Ngo ◽  
Stanislav Groysman ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Co2 Reduction ◽  
Pincer Complexes ◽  
Pincer Complex ◽  
Reduction Behaviour

The electrochemical properties of two Ni(NNN)X2 pincer complexes are reported where X = Cl or Br and NNN is N,N′-(2,6-diisopropylphenyl)bis-aldiminopyridine.

scholarly journals Manganese Tricarbonyl Complexes with Asymmetric 2-Iminopyridine Ligands: Toward Decoupling Steric and Electronic Factors in Electrocatalytic CO2 Reduction

2016 ◽  
Vol 55 (24) ◽  
pp. 12568-12582 ◽  
Author(s):  
Steven J. P. Spall ◽  
Theo Keane ◽  
Joanne Tory ◽  
Dean C. Cocker ◽  
Harry Adams ◽  
...  
Keyword(s):  
Co2 Reduction ◽  
Manganese Tricarbonyl

Elucidating the electronic structures of β-Ag2MoO4 and Ag2O nanocrystals via theoretical and experimental approaches towards electrochemical water splitting and CO2 reduction

2021 ◽  
Vol 23 (15) ◽  
pp. 9539-9552
Author(s):  
Afsaneh Zareie-Darmian ◽  
Hossein Farsi ◽  
Alireza Farrokhi ◽  
Reza Sarhaddi ◽  
Zhihai Li
Keyword(s):  
Experimental Study ◽  
Electronic Structure ◽  
Electrochemical Properties ◽  
Water Splitting ◽  
Electronic Structures ◽  
Co2 Reduction ◽  
Experimental Approaches ◽  
Electrochemical Water Splitting

In this paper, we demonstrate a combined theoretical and experimental study on the electronic structure, and the optical and electrochemical properties of β-Ag2MoO4 and Ag2O as significant Ag-containing compounds.

Electrocatalytic CO2 reduction at low overpotentials using iron(III) tetra(meso-thienyl)porphyrins

2019 ◽  
Author(s):  
Josh D. B. Koenig ◽  
Janina Willkomm ◽  
Roland Roesler ◽  
Warren Piers ◽  
Gregory C. Welch
Keyword(s):  
Electrochemical Properties ◽  
Co2 Reduction

<p>The optical and electrochemical properties, as well as the CO<sub>2</sub> reduction capability of two different iron(III) thienyl-porphyrins, iron(III) tetra(<i>meso</i>-thien-2-yl)porphyrin (<b>FeTThP</b>) and iron(III) tetra(<i>meso</i>-5-methylthien-2-yl)porphyrin (<b>FeTThMeP</b>), are directly compared to those of iron(III) tetra(<i>meso</i>-phenyl)porphyrin (<b>FeTPP</b>). Through exploitation of mesomeric stabilization effects, <b>FeTThP</b> and <b>FeTThMeP</b> both reduced CO<sub>2</sub> to CO with comparable faradaic efficiencies and TON<sub>CO</sub> <sub> </sub>relative to <b>FeTPP</b>, with an overpotential 150 mV lower than the benchmark catalyst. </p>

scholarly journals Electrocatalytic CO2 reduction at low overpotentials using iron(III) tetra(meso-thienyl)porphyrins

2019 ◽  
Author(s):  
Josh D. B. Koenig ◽  
Janina Willkomm ◽  
Roland Roesler ◽  
Warren Piers ◽  
Gregory C. Welch
Keyword(s):  
Electrochemical Properties ◽  
Co2 Reduction

<p>The optical and electrochemical properties, as well as the CO<sub>2</sub> reduction capability of two different iron(III) thienyl-porphyrins, iron(III) tetra(<i>meso</i>-thien-2-yl)porphyrin (<b>FeTThP</b>) and iron(III) tetra(<i>meso</i>-5-methylthien-2-yl)porphyrin (<b>FeTThMeP</b>), are directly compared to those of iron(III) tetra(<i>meso</i>-phenyl)porphyrin (<b>FeTPP</b>). Through exploitation of mesomeric stabilization effects, <b>FeTThP</b> and <b>FeTThMeP</b> both reduced CO<sub>2</sub> to CO with comparable faradaic efficiencies and TON<sub>CO</sub> <sub> </sub>relative to <b>FeTPP</b>, with an overpotential 150 mV lower than the benchmark catalyst. </p>

scholarly journals Enhanced Electrocatalytic CO2 Reduction at Lower Overpotentials Using Iron (III) Tetra(thienyl)porphyrin

2019 ◽  
Author(s):  
Josh D. B. Koenig ◽  
Janina Willkomm ◽  
Roland Roesler ◽  
Warren Piers ◽  
Gregory C. Welch
Keyword(s):  
Electrochemical Properties ◽  
Co2 Reduction ◽  
Faradaic Efficiency ◽  
Lower Overpotential

Iron(III) tetra(5,10,15,20-thienyl)porphyrin chloride (FeTThP) is introduced as a new CO<sub>2</sub> reduction catalyst. The optical and electrochemical properties, as well as the CO<sub>2</sub> reduction capabilities of FeTThP are directly compared to those of iron(III) tetra(5,10,15,20-phenyl)porphyrin chloride (FeTPP). Relative to FeTPP, the newly developed FeTThP achieves a higher TON<sub>CO</sub>, with comparable faradaic efficiency, using a much lower overpotential.

Sign in / Sign up

Export Citation Format

Share Document