Ambiguous electrocatalytic CO2 reduction behaviour of a nickel bis(aldimino)pyridine pincer complex

2016 ◽  
Vol 45 (39) ◽  
pp. 15285-15289 ◽  
Author(s):  
Remya Narayanan ◽  
Meaghan McKinnon ◽  
Blake R. Reed ◽  
Ken T. Ngo ◽  
Stanislav Groysman ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Co2 Reduction ◽  
Pincer Complexes ◽  
Pincer Complex ◽  
Reduction Behaviour

The electrochemical properties of two Ni(NNN)X2 pincer complexes are reported where X = Cl or Br and NNN is N,N′-(2,6-diisopropylphenyl)bis-aldiminopyridine.

Ni pincer complex catalytic hydroboration of CO2: a DFT study on the influence of borane reductants on the selective reduction

2021 ◽  
Author(s):  
Nana Ma ◽  
Qingli Xu ◽  
Chenhao Tu ◽  
Wenyue Guo ◽  
Guisheng Zhang
Keyword(s):  
Co2 Reduction ◽  
Selective Reduction ◽  
Dft Study ◽  
Pincer Complex

It has been reported that either the boryl formate (HCOOBR2), bis(boryl)acetal (R2BOCH2OBR2), or methoxy borane (R2BOCH3) product of CO2 reduction is selectively afforded adopting the Nickel (Ni) pincer catalyst by...

Conversion of CO2 from air into formate using amines and phosphorus-nitrogen PN3P-Ru(ii) pincer complexes

2018 ◽  
Vol 20 (18) ◽  
pp. 4201-4205 ◽  
Author(s):  
Chao Guan ◽  
Yupeng Pan ◽  
Eleanor Pei Ling Ang ◽  
Jinsong Hu ◽  
Changguang Yao ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Pincer Complexes ◽  
Pincer Complex

Effective conversion of carbon dioxide from air into formate by a phosphorus-nitrogen PN3P-Ru(ii) pincer complex.

scholarly journals Highly selective hydrogenation of amides catalysed by a molybdenum pincer complex: scope and mechanism

2019 ◽  
Vol 10 (45) ◽  
pp. 10566-10576 ◽  
Author(s):  
Thomas Leischner ◽  
Lluis Artús Suarez ◽  
Anke Spannenberg ◽  
Kathrin Junge ◽  
Ainara Nova ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Selective Hydrogenation ◽  
Pincer Complexes ◽  
Pincer Complex ◽  
First Time

A series of molybdenum pincer complexes has been shown for the first time to be active in the catalytic hydrogenation of amides.

POCOP-type cobalt and nickel pincer complexes bearing an appended phosphinite group

2020 ◽  
pp. 1-7
Author(s):  
Yingze Li ◽  
Jeanette A. Krause ◽  
Hairong Guan
Keyword(s):  
Pincer Complexes ◽  
X Ray ◽  
X Ray Crystallography ◽  
Pincer Complex ◽  
Group Structures ◽  
Cobalt And Nickel

The reaction of 1,3,5-(iPr2PO)3C6H3 with Co2(CO)8 leads to the isolation of a POCOP-type mononuclear pincer complex {κP,κC,κP-2,4,6-(iPr2PO)3C6H2}Co(CO)2 (1) or a tetranuclear species {κP-{κP,κC,κP-2,4,6-(iPr2PO)3C6H2}Co(CO)2}2Co2(CO)6 (2), depending on the ligand to cobalt ratio employed. The latter compound can be an impurity during the synthesis of {2,6-(iPr2PO)2-4-Me2N-C6H2}Co(CO)2, when the ligand precursor 5-(dimethylamino)resorcinol is contaminated with phloroglucinol due to incomplete monoamination. Similarly, the reaction of 1,3,5-(iPr2PO)3C6H3 with NiCl2 in the presence of 4-dimethylaminopyridine provides {κP,κC,κP-2,4,6-(iPr2PO)3C6H2}NiCl (3) bearing an appended phosphinite group. Structures 1–3 have been studied by X-ray crystallography.

Surprisingly big linker-dependence of activity and selectivity in CO2 reduction by an iridium(i) pincer complex

2020 ◽  
Vol 56 (64) ◽  
pp. 9126-9129 ◽  
Author(s):  
Gongfang Hu ◽  
Jianbing “Jimmy” Jiang ◽  
H. Ray Kelly ◽  
Adam J. Matula ◽  
Yueshen Wu ◽  
...  
Keyword(s):  
Co2 Reduction ◽  
Pincer Complex

Here, we report the quantitative electroreduction of CO2 to CO by a PNP-pincer iridium(i) complex bearing amino linkers in DMF/water. The activity and selectivity of the reduction greatly depend on the choice of linker within the ligand.

Electrochemical Properties and CO2-Reduction Ability of m-Terphenyl Isocyanide Supported Manganese Tricarbonyl Complexes

2016 ◽  
Vol 55 (23) ◽  
pp. 12400-12408 ◽  
Author(s):  
Douglas W. Agnew ◽  
Matthew D. Sampson ◽  
Curtis E. Moore ◽  
Arnold L. Rheingold ◽  
Clifford P. Kubiak ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Co2 Reduction ◽  
Manganese Tricarbonyl

Unsymmetrical nickel (PCN) pincer complexes with a benzothiazole side-arm: Synthesis, characterization and electrochemical properties

2021 ◽  
Vol 517 ◽  
pp. 120182
Author(s):  
Lapo Luconi ◽  
Giulia Tuci ◽  
Zufar N. Gafurov ◽  
Giorgio Mercuri ◽  
Alexey A. Kagilev ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Pincer Complexes

Synthesis and comparison of nickel, palladium, and platinum bis(N-heterocyclic carbene) pincer complexes for electrocatalytic CO2 reduction

2018 ◽  
Vol 47 (6) ◽  
pp. 1827-1840 ◽  
Author(s):  
J. A. Therrien ◽  
M. O. Wolf ◽  
B. O. Patrick
Keyword(s):  
Carbon Dioxide ◽  
Co2 Reduction ◽  
Pincer Complexes ◽  
Electrocatalytic Reduction

Nickel, palladium, and platinum bis(N-heterocyclic carbene) pincer complexes are synthesized, surveyed, and compared for electrocatalytic reduction of carbon dioxide.

Polyannulated Bis(N-heterocyclic carbene)palladium Pincer Complexes for Electrocatalytic CO2 Reduction

2015 ◽  
Vol 54 (24) ◽  
pp. 11721-11732 ◽  
Author(s):  
Jeffrey A. Therrien ◽  
Michael O. Wolf ◽  
Brian O. Patrick
Keyword(s):  
Co2 Reduction ◽  
Pincer Complexes
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