Solubility, Solvent Effect, and Solvation Performance of MBQ-167 in Aqueous Cosolvent Solutions

<div> <div> <div> <p>This article reviews prior work studying reaction kinetics in solution, with the goal of using this information to improve detailed kinetic modeling in the solvent phase. Both experimental and computational methods for calculating reaction rates in liquids are reviewed. Previous studies, which used such methods to determine solvent effects, are then analyzed based on reaction family. Many of these studies correlate kinetic solvent effect with one or more solvent parameters or properties of reacting species, but it is not always possible, and investigations are usually done on too few reactions and solvents to truly generalize. From these studies, we present suggestions on how best to use data to generalize solvent effects for many different reaction types in a high throughput manner. </p> </div> </div> </div>

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Influence of Ligands and Solvent Effect on the 4f-4f Absorption Transitions

Journal of Pure Applied and Industrial Physics ◽

10.29055/jpaip/299 ◽

2017 ◽

Vol 7 (12) ◽

pp. 428-430

Author(s):

Wakeel Ahmed Dar

Keyword(s):

Solvent Effect ◽

Absorption Transitions

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Isotope solvent effect on the hydrogenation of maleic acid

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19781832 ◽

1978 ◽

Vol 43 (7) ◽

pp. 1832-1837

Author(s):

Rostislav Kudláček ◽

Josef Cabicar ◽

Milan Buňata

Keyword(s):

Solvent Effect ◽

Maleic Acid

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Solvent effect on valence vibration of NH bond of acetanilides and phenylcarbamates

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19760430 ◽

1976 ◽

Vol 41 (2) ◽

pp. 430-432

Author(s):

V. Bekárek ◽

J. Jirkovský ◽

K. Pragerová ◽

J. Socha

Keyword(s):

Solvent Effect ◽

Valence Vibration

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Additive-multiplicative description of extrathermodynamic relations: Application to solvent effect

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19900634 ◽

1990 ◽

Vol 55 (3) ◽

pp. 634-643 ◽

Cited By ~ 2

Author(s):

Oldřich Pytela

Keyword(s):

Solvent Effect ◽

Additive Model ◽

Multiplicative Model ◽

Data Matrix ◽

Statistical Parameters ◽

Model Application ◽

Mutual Correlation ◽

Linear Free Energy ◽

Cross Terms ◽

Energy Relationships

The paper is focused on evaluation of significance of the additive-multiplicative model of extrathermodynamic relations (linear free energy relationships) as compared with the additive model. Application of the method of conjugated deviations to a data matrix describing manifestations of solvent effects in 367 processes in solutions (6 334 data) has shown that introduction of cross-terms into the additive model is statistically significant for a model with two and particularly three parameters. At the same time the calculation has provided a new set of statistical parameters for description of solvent effect with application of the additive-multiplicative model. Compared with an analogous set designated for the additive model, the new parameters show a lower mutual correlation, retaining the same nature of the properties described, i.e. polarity-acidity (PAC parameter), polarity-basicity (PBC), and polarity-polarizability (PPC).

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