Experimental and Theoretical Study of the Kinetics and Mechanism of the Reaction of Chlorine Atoms with CH3CHClCH3 and CD3CDClCD3

2018 ◽  
Vol 122 (2) ◽  
pp. 470-481 ◽  
Author(s):  
Dariusz Sarzyński ◽  
Łukasz Fojcik ◽  
Zdzisław Latajka
Keyword(s):  
Theoretical Study ◽  
Kinetics And Mechanism ◽  
Chlorine Atoms ◽  
Mechanism Of The Reaction

Experimental and Theoretical Study of the Kinetics and Mechanism of the Reaction of OH Radicals with Dimethyl Ether

2013 ◽  
Vol 117 (44) ◽  
pp. 11142-11154 ◽  
Author(s):  
S. A. Carr ◽  
T. J. Still ◽  
M. A. Blitz ◽  
A. J. Eskola ◽  
M. J. Pilling ◽  
...  
Keyword(s):  
Dimethyl Ether ◽  
Theoretical Study ◽  
Kinetics And Mechanism ◽  
Oh Radicals ◽  
Mechanism Of The Reaction

Kinetics and Mechanism of the Reaction of Chlorine Atoms withn-Pentanal

2008 ◽  
Vol 112 (8) ◽  
pp. 1741-1746 ◽  
Author(s):  
E. Iwasaki ◽  
T. Nakayama ◽  
Y. Matsumi ◽  
K. Takahashi ◽  
T. J. Wallington ◽  
...  
Keyword(s):  
Kinetics And Mechanism ◽  
Chlorine Atoms ◽  
Mechanism Of The Reaction

Kinetics and mechanism of the reaction of propylene oxide with chlorine atoms and hydroxy radicals

2011 ◽  
Vol 43 (9) ◽  
pp. 507-521 ◽  
Author(s):  
Srikar Middala ◽  
Sean Campbell ◽  
Catalina Olea ◽  
Austen Scruggs ◽  
Alam S. Hasson
Keyword(s):  
Propylene Oxide ◽  
Kinetics And Mechanism ◽  
Chlorine Atoms ◽  
Hydroxy Radicals ◽  
Mechanism Of The Reaction

Kinetics and mechanism of the reaction of iron(III) with 6-methyl-2,4-heptanedione and 3,5-heptanedione

1990 ◽  
Vol 55 (8) ◽  
pp. 1984-1990 ◽  
Author(s):  
José M. Hernando ◽  
Olimpio Montero ◽  
Carlos Blanco
Keyword(s):  
Aqueous Solution ◽  
Metal Ion ◽  
Activation Parameters ◽  
Enol Form ◽  
Kinetics And Mechanism ◽  
Kinetic Constants ◽  
Steric Factors ◽  
Kinetics Of ◽  
Mechanism Of The Reaction

The kinetics of the reactions of iron(III) with 6-methyl-2,4-heptanedione and 3,5-heptanedione to form the corresponding monocomplexes have been studied spectrophotometrically in the range 5 °C to 16 °C at I 25 mol l-1 in aqueous solution. In the proposed mechanism for the two complexes, the enol form reacts with the metal ion by parallel acid-independent and inverse-acid paths. The kinetic constants for both pathways have been calculated at five temperatures. Activation parameters have also been calculated. The results are consistent with an associative activation for Fe(H2O)63+ and dissociative activation for Fe(H2O)5(OH)2+. The differences in the results for the complexes of heptanediones studied are interpreted in terms of steric factors.

Kinetics and mechanism of the reaction of OH with ClO

2001 ◽  
Vol 33 (10) ◽  
pp. 587-599 ◽  
Author(s):  
Yuri Bedjanian ◽  
V�ronique Riffault ◽  
Georges Le Bras
Keyword(s):  
Kinetics And Mechanism ◽  
Mechanism Of The Reaction
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