Experimental and Theoretical Study of the Kinetics and Mechanism of the Reaction of OH Radicals with Dimethyl Ether

2013 ◽  
Vol 117 (44) ◽  
pp. 11142-11154 ◽  
Author(s):  
S. A. Carr ◽  
T. J. Still ◽  
M. A. Blitz ◽  
A. J. Eskola ◽  
M. J. Pilling ◽  
...  
Keyword(s):  
Dimethyl Ether ◽  
Theoretical Study ◽  
Kinetics And Mechanism ◽  
Oh Radicals ◽  
Mechanism Of The Reaction

Photochemistry of 2,2-dichloroethanol: kinetics and mechanism of the reaction with Cl atoms and OH radicals

2020 ◽  
Vol 22 (3) ◽  
pp. 719-727
Author(s):  
Mads. P. Sulbaek Andersen ◽  
Sofie A. Hass ◽  
Kjertan Lyster ◽  
Mila Avetikyan ◽  
Timothy J. Wallington ◽  
...  
Keyword(s):  
Environmental Impact ◽  
Atmospheric Chemistry ◽  
Kinetics And Mechanism ◽  
Oh Radicals ◽  
Smog Chamber ◽  
Ftir Study ◽  
Cl Atoms ◽  
Mechanism Of The Reaction

Smog chamber/FTIR study investigates the atmospheric chemistry and environmental impact of 2,2-dichloroethanol.

Kinetics and mechanism of the reaction of iron(III) with 6-methyl-2,4-heptanedione and 3,5-heptanedione

1990 ◽  
Vol 55 (8) ◽  
pp. 1984-1990 ◽  
Author(s):  
José M. Hernando ◽  
Olimpio Montero ◽  
Carlos Blanco
Keyword(s):  
Aqueous Solution ◽  
Metal Ion ◽  
Activation Parameters ◽  
Enol Form ◽  
Kinetics And Mechanism ◽  
Kinetic Constants ◽  
Steric Factors ◽  
Kinetics Of ◽  
Mechanism Of The Reaction

The kinetics of the reactions of iron(III) with 6-methyl-2,4-heptanedione and 3,5-heptanedione to form the corresponding monocomplexes have been studied spectrophotometrically in the range 5 °C to 16 °C at I 25 mol l-1 in aqueous solution. In the proposed mechanism for the two complexes, the enol form reacts with the metal ion by parallel acid-independent and inverse-acid paths. The kinetic constants for both pathways have been calculated at five temperatures. Activation parameters have also been calculated. The results are consistent with an associative activation for Fe(H2O)63+ and dissociative activation for Fe(H2O)5(OH)2+. The differences in the results for the complexes of heptanediones studied are interpreted in terms of steric factors.

Atmospheric Chemistry of CH3CH2OCH3: Kinetics and Mechanism of Reactions with Cl Atoms and OH Radicals

2016 ◽  
Vol 49 (1) ◽  
pp. 10-20 ◽  
Author(s):  
Mads P. Sulbaek Andersen ◽  
Sissel Bjørn Svendsen ◽  
Freja From Østerstrøm ◽  
Ole John Nielsen
Keyword(s):  
Atmospheric Chemistry ◽  
Kinetics And Mechanism ◽  
Oh Radicals ◽  
Cl Atoms

Theoretical Study on the Reaction of OH Radicals with Polychlorinated Dibenzo-p-dioxins

2004 ◽  
Vol 108 (4) ◽  
pp. 607-614 ◽  
Author(s):  
Jung Eun Lee ◽  
Wonyong Choi ◽  
Byung Jin Mhin ◽  
Krishnan Balasubramanian
Keyword(s):  
Theoretical Study ◽  
Oh Radicals

Kinetics and mechanism of the reaction of OH with ClO

2001 ◽  
Vol 33 (10) ◽  
pp. 587-599 ◽  
Author(s):  
Yuri Bedjanian ◽  
V�ronique Riffault ◽  
Georges Le Bras
Keyword(s):  
Kinetics And Mechanism ◽  
Mechanism Of The Reaction

Atmospheric Degradation of CF3OCFCF2:  Kinetics and Mechanism of Its Reaction with OH Radicals and Cl Atoms

2000 ◽  
Vol 104 (13) ◽  
pp. 2925-2930 ◽  
Author(s):  
M. Mashino ◽  
M. Kawasaki ◽  
T. J. Wallington ◽  
M. D. Hurley
Keyword(s):  
Kinetics And Mechanism ◽  
Oh Radicals ◽  
Atmospheric Degradation ◽  
Cl Atoms
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