Theoretical Study of the Metal-Controlled Dehydrogenation Mechanism of MN2H3BH3(M = Li, Na, K): A New Family of Hydrogen Storage Material

2018 ◽  
Vol 122 (5) ◽  
pp. 1344-1349 ◽  
Author(s):  
Tong Li ◽  
Jian-Guo Zhang
2020 ◽  
Vol 26 ◽  
pp. 198-202 ◽  
Author(s):  
Khai Chen Tan ◽  
Yang Yu ◽  
Ruting Chen ◽  
Teng He ◽  
Zijun Jing ◽  
...  

2021 ◽  
Vol 765 ◽  
pp. 138277
Author(s):  
Pingping Liu ◽  
Yafei Zhang ◽  
Xiangjun Xu ◽  
Fangming Liu ◽  
Jibiao Li

2012 ◽  
Vol 512-515 ◽  
pp. 1438-1441 ◽  
Author(s):  
Hong Min Kan ◽  
Ning Zhang ◽  
Xiao Yang Wang ◽  
Hong Sun

An overview of recent advances in hydrogen storage is presented in this review. The main focus is on metal hydrides, liquid-phase hydrogen storage material, alkaline earth metal NC/polymer composites and lithium borohydride ammoniate. Boron-nitrogen-based liquid-phase hydrogen storage material is a liquid under ambient conditions, air- and moisture-stable, recyclable and releases H2controllably and cleanly. It is not a solid material. It is easy storage and transport. The development of a liquid-phase hydrogen storage material has the potential to take advantage of the existing liquid-based distribution infrastructure. An air-stable composite material that consists of metallic Mg nanocrystals (NCs) in a gas-barrier polymer matrix that enables both the storage of a high density of hydrogen and rapid kinetics (loading in <30 min at 200°C). Moreover, nanostructuring of Mg provides rapid storage kinetics without using expensive heavy-metal catalysts. The Co-catalyzed lithium borohydride ammoniate, Li(NH3)4/3BH4 releases 17.8 wt% of hydrogen in the temperature range of 135 to 250 °C in a closed vessel. This is the maximum amount of dehydrogenation in all reports. These will reduce economy cost of the global transition from fossil fuels to hydrogen energy.


ChemInform ◽  
2009 ◽  
Vol 40 (36) ◽  
Author(s):  
Thomas Huegle ◽  
Moritz F. Kuehnel ◽  
Dieter Lentz

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