Theoretical Investigation of the Heterojunction Effect on the Catalytic Activity and Selectivity of an Au@NiO Core–Shell Catalyst in Aerobic Oxidation

A Fe3O4/SiO2/PATL/MnO2 core/shell nanocomposite was synthesized via an ultrasound-assisted method and its catalytic activity for the aerobic oxidation of alcohols to aldehydes and ketones was evaluated .

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The design and catalytic performance of molybdenum active sites on an MCM-41 framework for the aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran

Catalysis Science & Technology ◽

10.1039/c8cy02291g ◽

2019 ◽

Vol 9 (3) ◽

pp. 811-821 ◽

Cited By ~ 7

Author(s):

Zhao-Meng Wang ◽

Li-Juan Liu ◽

Bo Xiang ◽

Yue Wang ◽

Ya-Jing Lyu ◽

...

Keyword(s):

Catalytic Activity ◽

Active Sites ◽

Aerobic Oxidation ◽

Catalytic Performance ◽

Mcm 41

The catalytic activity decreases as –(SiO)3Mo(OH)(O) > –(SiO)2Mo(O)2 > –(O)4–MoO.

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Theoretical investigation on dependence of luminescence properties from CdS/ZnS core-shell quantum dots on core size and quantum confinement

10.1063/5.0052365 ◽

2021 ◽

Author(s):

Sanjib Kabi ◽

Saikat Chattopadhyay ◽

Sanat Kumar Das

Keyword(s):

Quantum Dots ◽

Theoretical Investigation ◽

Quantum Confinement ◽

Luminescence Properties ◽

Core Shell ◽

Core Size

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On the selective aerobic oxidation of benzyl alcohol with Pd/Au-nanoparticles in batch and flow

Nanotechnology Reviews ◽

10.1515/ntrev-2012-0085 ◽

2014 ◽

Vol 3 (1) ◽

pp. 99-110 ◽

Cited By ~ 2

Author(s):

Hannes Alex ◽

Norbert Steinfeldt ◽

Klaus Jähnisch ◽

Matthias Bauer ◽

Sandra Hübner

Keyword(s):

Catalytic Activity ◽

Benzyl Alcohol ◽

Aerobic Oxidation ◽

X Ray ◽

X Ray Scattering ◽

Oxidation Of Benzyl Alcohol ◽

Transmission Electron ◽

Vis Spectroscopy ◽

Selective Aerobic Oxidation

AbstractNanoparticles (NP) have specific catalytic properties, which are influenced by parameters like their size, shape, or composition. Bimetallic NPs, composed of two metal elements can show an improved catalytic activity compared to the monometallic NPs. We, herein, report on the selective aerobic oxidation of benzyl alcohol catalyzed by unsupported Pd/Au and Pd NPs at atmospheric pressure. NPs of varying compositions were synthesized and characterized by UV/Vis spectroscopy, transmission electron microscopy (TEM), and small-angle X-ray scattering (SAXS). The NPs were tested in the model reaction regarding their catalytic activity, stability, and recyclability in batch and continuous procedure. Additionally, in situ extended X-ray absorption fine structure (EXAFS) measurements were performed in order to get insight in the process during NP catalysis.

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Theoretical investigation onto the reaction mechanism of dry reforming of methane on core-shell Cu-Ni-Pt ternary alloy clusters

Chemical Physics Letters ◽

10.1016/j.cplett.2021.138975 ◽

2021 ◽

pp. 138975

Author(s):

Lianyang Zhang ◽

Yue Meng ◽

Bo Xie ◽

Shengjie Xia

Keyword(s):

Reaction Mechanism ◽

Ternary Alloy ◽

Theoretical Investigation ◽

Dry Reforming ◽

Dry Reforming Of Methane ◽

Core Shell ◽

Alloy Clusters

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A novel copper(ii)–lanthanum(iii) metal organic framework as a selective catalyst for the aerobic oxidation of benzylic hydrocarbons and cycloalkenes

Catalysis Science & Technology ◽

10.1039/c5cy01448d ◽

2016 ◽

Vol 6 (11) ◽

pp. 3727-3736 ◽

Cited By ~ 26

Author(s):

P. Cancino ◽

A. Vega ◽

Andrea Santiago-Portillo ◽

Sergio Navalon ◽

Mercedes Alvaro ◽

...

Keyword(s):

Catalytic Activity ◽

Metal Organic Framework ◽

Aerobic Oxidation ◽

Selective Catalyst ◽

Pyridinedicarboxylic Acid ◽

Metal Organic ◽

Organic Framework

The synthesis and catalytic activity of a novel heteronuclear CuII and LaIII metal organic framework (MOF) having pyridinedicarboxylic acid (CuLa-MOF) is reported.

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