Visible Light Mediated Controlled Radical Polymerization in the Absence of Exogenous Radical Sources or Catalysts

2015 ◽  
Vol 48 (12) ◽  
pp. 3864-3872 ◽  
Author(s):  
Thomas G. McKenzie ◽  
Qiang Fu ◽  
Edgar H. H. Wong ◽  
Dave E. Dunstan ◽  
Greg G. Qiao
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Controlled Radical Polymerization

Organocatalytic PET-RAFT Polymerization with ppm of Organic Photocatalyst under Visible Light

2021 ◽  
Author(s):  
Qiang Ma ◽  
Xun Zhang ◽  
Yu Jiang ◽  
Junqiang Lin ◽  
Bernadette Graff ◽  
...  
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Raft Polymerization ◽  
Controlled Radical Polymerization ◽  
Polymerization Process ◽  
Light Control

The development of light-mediated controlled radical polymerization has benefited from the discovery of novel photocatalysts, which could allow a precise light control over the polymerization process and the production of...

scholarly journals Precise growth of polymer brushes on silica-based nanocomposites via visible-light-regulated controlled radical polymerization

2019 ◽  
Vol 7 (11) ◽  
pp. 6173-6179 ◽  
Author(s):  
Xue Li ◽  
Sunjie Ye ◽  
Ya Huang ◽  
Jia Le Li ◽  
Tao Cai
Keyword(s):  
Physicochemical Properties ◽  
Visible Light ◽  
Radical Polymerization ◽  
Polymer Nanocomposites ◽  
Polymer Brushes ◽  
Controlled Radical Polymerization ◽  
Crucial Importance ◽  
Grafted Polymer ◽  
Precise Control

Precise control over molecular variables of grafted polymer brushes is of crucial importance for obtaining polymer nanocomposites with desirable architectures and physicochemical properties, yet it remains a significant synthetic challenge.

scholarly journals A well-defined, versatile photoinitiator (salen)Co–CO2CH3 for visible light-initiated living/controlled radical polymerization

2015 ◽  
Vol 6 (5) ◽  
pp. 2979-2988 ◽  
Author(s):  
Yaguang Zhao ◽  
Mengmeng Yu ◽  
Shuailin Zhang ◽  
Zhenqiang Wu ◽  
Yuchu Liu ◽  
...  
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Controlled Radical Polymerization ◽  
Salen Complex ◽  
Living Controlled Radical Polymerization

A well-defined organocobalt salen complex (salen)Co–CO2CH3 is used as a versatile photoinitiator for visible light-initiated living radical polymerization.

Benzoyl Phenyltelluride as Highly Reactive Visible-Light TERP-Reagent for Controlled Radical Polymerization

2014 ◽  
Vol 47 (16) ◽  
pp. 5526-5531 ◽  
Author(s):  
Stephan Benedikt ◽  
Norbert Moszner ◽  
Robert Liska
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Controlled Radical Polymerization

scholarly journals Visible-light-mediated, additive-free, and open-to-air controlled radical polymerization of acrylates and acrylamides

2019 ◽  
Vol 10 (13) ◽  
pp. 1585-1590 ◽  
Author(s):  
Jessica R. Lamb ◽  
K. Peter Qin ◽  
Jeremiah A. Johnson
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Controlled Radical Polymerization

Polymerizing through oxygen in open vials without any additional additives expands the utility of photocontrolled iniferter polymerization.

Structure-Property Relationships of Core-Substituted Diaryl Dihydrophenazine Organic Photoredox Catalysts and their Application in O-ATRP

2021 ◽  
Author(s):  
Mariel Jene Price ◽  
Katrina Puffer ◽  
Max Kudisch ◽  
Declan Knies ◽  
Garret Miyake
Keyword(s):  
Visible Light ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Controlled Radical Polymerization ◽  
Low Energy ◽  
Atom Transfer ◽  
Structure Property ◽  
Structure Property Relationships

Photoinduced organocatalyzed atom-transfer radical polymerization (O-ATRP) is a controlled radical polymerization technique that can be driven using low-energy, visible light and makes use of organic photocatalysts. Limitations of O-ATRP have...

Visible Light Induced Living/Controlled Radical Polymerization of Acrylates Catalyzed by Cobalt Porphyrins

2014 ◽  
Vol 47 (18) ◽  
pp. 6238-6245 ◽  
Author(s):  
Yaguang Zhao ◽  
Mengmeng Yu ◽  
Shuailin Zhang ◽  
Yuchu Liu ◽  
Xuefeng Fu
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Controlled Radical Polymerization ◽  
Cobalt Porphyrins ◽  
Living Controlled Radical Polymerization

scholarly journals Controlled Radical Polymerization of Acrylates Regulated by Visible Light

2014 ◽  
Vol 3 (6) ◽  
pp. 580-584 ◽  
Author(s):  
Nicolas J. Treat ◽  
Brett P. Fors ◽  
John W. Kramer ◽  
Matthew Christianson ◽  
Chien-Yang Chiu ◽  
...  
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Controlled Radical Polymerization

Visible-Light Hypervalent Iodide Carboxylate Photo(trifluoro)methylations and Controlled Radical Polymerization of Fluorinated Alkenes

2013 ◽  
Vol 125 (38) ◽  
pp. 10211-10214 ◽  
Author(s):  
Alexandru D. Asandei ◽  
Olumide I. Adebolu ◽  
Christopher P. Simpson ◽  
Joon-Sung Kim
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Controlled Radical Polymerization ◽  
Hypervalent Iodide
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