Solvent-Free Synthesis of the Polymer Electrolyte via Photo-Controlled Radical Polymerization: Toward Ultrafast In-Built Fabrication of Solid-State Batteries under Visible Light

2021 ◽  
Vol 13 (7) ◽  
pp. 8426-8434 ◽  
Author(s):  
Peng Wen ◽  
Yucheng Zhao ◽  
Zongtao Wang ◽  
Jun Lin ◽  
Mao Chen ◽  
...  
Keyword(s):  
Solid State ◽  
Visible Light ◽  
Polymer Electrolyte ◽  
Radical Polymerization ◽  
Controlled Radical Polymerization ◽  
Solvent Free ◽  
Solid State Batteries ◽  
Solvent Free Synthesis

Room Temperature Solvent-Free Synthesis of Monodisperse Magnetite Nanocrystals

2006 ◽  
Vol 6 (3) ◽  
pp. 852-856 ◽  
Author(s):  
X. R. Ye ◽  
C. Daraio ◽  
C. Wang ◽  
J. B. Talbot ◽  
S. Jin
Keyword(s):  
Oleic Acid ◽  
Solid State ◽  
Large Scale ◽  
Room Temperature ◽  
Solvent Free ◽  
Two Dimensional ◽  
New Process ◽  
High Boiling Point ◽  
Magnetite Nanocrystals ◽  
Solvent Free Synthesis

We have successfully demonstrated a facile, solvent-free synthesis of highly crystalline and monodisperse Fe3O4 nanocrystallites at ambient temperature avoiding any heating. Solid state reaction of inorganic Fe(II) and Fe(III) salts with NaOH was found to produce highly crystalline Fe3O4 nanoparticles. The reaction, if carried out in the presence of surfactant such as oleic acid–oleylamine adduct, generated monodisperse Fe3O4 nanocrystals extractable directly from the reaction mixture. The extracted nanoparticles were capable of forming self-assembled, two-dimensional and uniform periodic array. The new process utilizes inexpensive and nontoxic starting materials, and does not require a use of high boiling point and toxic solvents, thus is amenable to an environmentally desirable, large-scale synthesis of nanocrystals.

Organocatalytic PET-RAFT Polymerization with ppm of Organic Photocatalyst under Visible Light

2021 ◽  
Author(s):  
Qiang Ma ◽  
Xun Zhang ◽  
Yu Jiang ◽  
Junqiang Lin ◽  
Bernadette Graff ◽  
...  
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Raft Polymerization ◽  
Controlled Radical Polymerization ◽  
Polymerization Process ◽  
Light Control

The development of light-mediated controlled radical polymerization has benefited from the discovery of novel photocatalysts, which could allow a precise light control over the polymerization process and the production of...

Ceramic-Doped in Cross-Linked Solid Polymer Electrolyte for Solid-State Batteries

2020 ◽  
Vol MA2020-01 (2) ◽  
pp. 250-250
Author(s):  
Lamartine Meda ◽  
Gaind P. Pandey ◽  
Jere A. Williams ◽  
Arielle Lebean ◽  
Asha Ain Abiade ◽  
...  
Keyword(s):  
Solid State ◽  
Polymer Electrolyte ◽  
Solid Polymer Electrolyte ◽  
Solid Polymer ◽  
Solid State Batteries

Highly Chemoselective Solvent-Free Synthesis of 1,3,5-Triaryl-1,5-diketones: Crystallographic Investigation and Intramolecular Weak Bifurcated H Bonds Involving Aliphatic C–H Group

Synlett ◽  
2019 ◽  
Vol 30 (19) ◽  
pp. 2143-2147
Author(s):  
Zhongyou Yin ◽  
Changkun Xiong ◽  
Jianxin Guo ◽  
Xiaoyun Hu ◽  
Zixing Shan ◽  
...  
Keyword(s):  
Solid State ◽  
Decisive Role ◽  
Solvent Free ◽  
Dihedral Angles ◽  
Crystallographic Investigation ◽  
Structural Arrangement ◽  
Bond Lengths ◽  
Solvent Free Conditions ◽  
Solvent Free Synthesis

Several 1,3,5-triaryl-1,5-diketones have been chemoselectively synthesized under solvent-free conditions. It was found that intramolecular weak bifurcated H-bonds interaction of aliphatic C–H group plays a decisive role in the structural arrangement of 3-(2,6-dichlorophenyl)-1,5-diphenylpentane-1,5-dione in a solid state resulting in significant impact on the corresponding bond lengths and dihedral angles.

scholarly journals Precise growth of polymer brushes on silica-based nanocomposites via visible-light-regulated controlled radical polymerization

2019 ◽  
Vol 7 (11) ◽  
pp. 6173-6179 ◽  
Author(s):  
Xue Li ◽  
Sunjie Ye ◽  
Ya Huang ◽  
Jia Le Li ◽  
Tao Cai
Keyword(s):  
Physicochemical Properties ◽  
Visible Light ◽  
Radical Polymerization ◽  
Polymer Nanocomposites ◽  
Polymer Brushes ◽  
Controlled Radical Polymerization ◽  
Crucial Importance ◽  
Grafted Polymer ◽  
Precise Control

Precise control over molecular variables of grafted polymer brushes is of crucial importance for obtaining polymer nanocomposites with desirable architectures and physicochemical properties, yet it remains a significant synthetic challenge.

A polyoxometalate-based polymer electrolyte with an improved electrode interface and ion conductivity for high-safety all-solid-state batteries

2019 ◽  
Vol 7 (26) ◽  
pp. 15924-15932 ◽  
Author(s):  
Xiangfei Yuan ◽  
Cui Sun ◽  
Jia-Ning Duan ◽  
Jingmin Fan ◽  
Ruming Yuan ◽  
...  
Keyword(s):  
Solid State ◽  
Polymer Electrolyte ◽  
Ion Conductivity ◽  
Solid State Batteries ◽  
Electrode Interface ◽  
All Solid State Batteries

By combining inorganic LVC with organic PEO matrix, a polyoxometalate-based polymer electrolyte (PPE) was constructed for solid state batteries.

scholarly journals A well-defined, versatile photoinitiator (salen)Co–CO2CH3 for visible light-initiated living/controlled radical polymerization

2015 ◽  
Vol 6 (5) ◽  
pp. 2979-2988 ◽  
Author(s):  
Yaguang Zhao ◽  
Mengmeng Yu ◽  
Shuailin Zhang ◽  
Zhenqiang Wu ◽  
Yuchu Liu ◽  
...  
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Controlled Radical Polymerization ◽  
Salen Complex ◽  
Living Controlled Radical Polymerization

A well-defined organocobalt salen complex (salen)Co–CO2CH3 is used as a versatile photoinitiator for visible light-initiated living radical polymerization.

Solid-state batteries designed with high ion conductive composite polymer electrolyte and silicon anode

2021 ◽  
Vol 43 ◽  
pp. 165-171
Author(s):  
Jun Pan ◽  
Huili Peng ◽  
Yehao Yan ◽  
Yuzhou Bai ◽  
Jian Yang ◽  
...  
Keyword(s):  
Solid State ◽  
Polymer Electrolyte ◽  
Silicon Anode ◽  
Composite Polymer Electrolyte ◽  
Composite Polymer ◽  
Conductive Composite ◽  
Solid State Batteries

Benzoyl Phenyltelluride as Highly Reactive Visible-Light TERP-Reagent for Controlled Radical Polymerization

2014 ◽  
Vol 47 (16) ◽  
pp. 5526-5531 ◽  
Author(s):  
Stephan Benedikt ◽  
Norbert Moszner ◽  
Robert Liska
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Controlled Radical Polymerization
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