Heteroleptic Ni(II) Complexes Bearing a Bulky Yet Flexible IBiox-6 Ligand: Improved Selectivity in Cross-Electrophile Coupling of Benzyl Chlorides with Aryl Chlorides/Fluorides

2020 ◽  
Vol 39 (19) ◽  
pp. 3540-3545
Author(s):  
Zheng-Wang Shen ◽  
Die-Die Meng ◽  
Sajid Imran ◽  
Chun-Hui Yan ◽  
Hong-Mei Sun
Keyword(s):  
Aryl Chlorides ◽  
Benzyl Chlorides

Nickel-Catalyzed Reductive Cross-Coupling of Benzyl Chlorides with Aryl Chlorides/Fluorides: A One-Pot Synthesis of Diarylmethanes

2016 ◽  
Vol 18 (12) ◽  
pp. 2860-2863 ◽  
Author(s):  
Jie Zhang ◽  
Gusheng Lu ◽  
Jin Xu ◽  
Hongmei Sun ◽  
Qi Shen
Keyword(s):  
Cross Coupling ◽  
One Pot ◽  
Aryl Chlorides ◽  
One Pot Synthesis ◽  
Benzyl Chlorides

Mesoporous Ethane−Silicas Functionalized with a Bulky N-Heterocyclic Carbene for Suzuki−Miyaura Coupling of Aryl Chlorides and Benzyl Chlorides

2010 ◽  
Vol 114 (50) ◽  
pp. 22221-22229 ◽  
Author(s):  
Hengquan Yang ◽  
Xiaojing Han ◽  
Guang Li ◽  
Zhancheng Ma ◽  
Yajuan Hao
Keyword(s):  
Aryl Chlorides ◽  
Benzyl Chlorides

Chiral Mn(III) Salen Complex Immobilized on CuFe2O4@SiO2-NH2 NPs: A Cheap and Efficient Catalyst for N-arylation of Aryl Halides and Phenylboronic Acid Under Mild Conditions

2020 ◽  
Vol 17 (11) ◽  
pp. 857-863
Author(s):  
Mohammad Ali Nasseri ◽  
Seyyedeh Ameneh Alavi ◽  
Milad Kazemnejadi ◽  
Ali Allahresani
Keyword(s):  
Phenylboronic Acid ◽  
Significant Loss ◽  
Aryl Halides ◽  
Coupling Reactions ◽  
Efficient Catalyst ◽  
Aryl Chlorides ◽  
Mild Conditions ◽  
Cross Coupling Reactions ◽  
Salen Complex ◽  
Ft Ir

A convenient and efficient chiral CuFe2O4@SiO2-Mn(III) Ch.salen nanocatalyst has been developed for the C-N cross-coupling reactions of aryl halides/ phenylboronic acid with N-heterocyclic compounds in water and/or DMSO under mild conditions. The catalyst could be applied for the N-arylation of a variety of nitrogen-containing heterocycles with aryl chlorides, bromides, iodides and phenylboronic acid under mild conditions. Moderate to good yields were achieved for all substrates. The structure of catalyst was characterized using various techniques including FT-IR, FE-SEM, EDX, XRD, TEM and TGA. The catalyst can be simply recovered and reused for several times without significant loss of activity.

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