Rhodium and Iridium Complexes Bearing “Capping Arene” Ligands: Synthesis and Characterization

2021 ◽  
Author(s):  
Shunyan Gu ◽  
Charles B. Musgrave ◽  
Zoë M. Gehman ◽  
Ke Zhang ◽  
Diane A. Dickie ◽  
...  
Keyword(s):  
Synthesis And Characterization ◽  
Iridium Complexes ◽  
Arene Ligands

Synthesis and characterization of phosphorescent platinum and iridium complexes with cyclometalated corannulene

2015 ◽  
Vol 44 (18) ◽  
pp. 8456-8466 ◽  
Author(s):  
John W. Facendola ◽  
Martin Seifrid ◽  
Jay Siegel ◽  
Peter I. Djurovich ◽  
Mark E. Thompson
Keyword(s):  
Synthesis And Characterization ◽  
Iridium Complexes

Novel, emissive Pt(ii) and Ir(iii) complexes are the first to have measured rates of inversion of cyclometalated corannulene.

Synthesis and characterization of new blue light emitting iridium complexes containing a trimethylsilyl group

2012 ◽  
Vol 22 (42) ◽  
pp. 22721 ◽  
Author(s):  
Chul Young Kim ◽  
Dong-Gwang Ha ◽  
Hyun Hee Kang ◽  
Hui-Jun Yun ◽  
Soon-Ki Kwon ◽  
...  
Keyword(s):  
Blue Light ◽  
Synthesis And Characterization ◽  
Iridium Complexes ◽  
Trimethylsilyl Group ◽  
Light Emitting

Synthesis and characterization of a Bi10O8(OAr)16 oxo-cluster supported by p-tert-butylcalix[5]arene ligands

2016 ◽  
Vol 45 (34) ◽  
pp. 13399-13405 ◽  
Author(s):  
Daniel Mendoza-Espinosa
Keyword(s):  
Synthesis And Characterization ◽  
Dimeric Complex ◽  
Arene Ligands

Wet [tBuC5(Bn)(H)4] ligand reacts with excess of Bi[N(SiMe3)2]3 to yield the dimeric complex 1 [Bi{tBuC5(Bn)(H)}]2 and cluster 2 [Bi10O8{tBuC5(Bn)(H)}4]. Complex 2 features multicoordinated bismuth(iii) centers in an overall Bi10O8(OAr)16 core which represents the largest bismuth oxo-cluster supported by calix[n]arene ligands to date.

scholarly journals A pyrazine amide – 4-aminoquinoline hybrid and its rhodium and iridium pentamethylcyclopentadienyl complexes; evaluation of anti-mycobacterial and anti-plasmodial activities

2017 ◽  
Vol 61 (2) ◽  
Author(s):  
Erik Ekengard ◽  
Ida Bergare ◽  
Josefine Hansson ◽  
Isa Doverbratt ◽  
Magda Monari ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Free Ligand ◽  
Molecular Structures ◽  
Synthesis And Characterization ◽  
Iridium Complexes

The synthesis and characterization of N-(2-((7-chloroquinolin-4-yl)amino)ethyl)pyrazine-2-carboxamide (<strong>L</strong>), an aminoquinoline – pyrazinamide hybrid, and the complexes (N-(2-((7-chloroquinolin-4-yl)amino)ethyl)pyrazine-2-carboxamide)(cyclopentadienyl) chlorido-rhodium or iridium hexafluorophosphate ([M(<strong>L</strong>)(Cp*)Cl] PF<sub>6</sub>; M = Rh, Ir) and the corresponding chlorido salts ([M(<strong>L</strong>)(Cp*) Cl]Cl; M = Rh, Ir) are described. The ligand and the hexafluorophosphate salts of the metal complexes have been evaluated for anti-plasmodial and anti-mycobacterial activity. The rhodium and the iridium complexes were significantly more active against <em>M. tuberculosis</em> than the free ligand. The crystallographically determined molecular structures of complexes (N-(2-((7-chloroquinolin-4-yl)amino)ethyl)pyrazine-2-carboxamide)(cyclopentadienyl)chlororhodium hexafluoro-phosphate and (N-(2-((7-chloroquinolin-4-yl)amino)ethyl)pyrazine-2-carboxamide)(cyclopentadienyl)chloro-iridium chloride are presented.

Synthesis and Characterization of New Iridium Complexes with the (4S)-2-[2-(Diphenylphosphanyl)phenyl]-4-isopropyl-1,3-oxazoline Ligand that Catalyze Asymmetric Michael Reactions.

ChemInform ◽  
2005 ◽  
Vol 36 (37) ◽  
Author(s):  
Daniel Carmona ◽  
Joaquina Ferrer ◽  
Monica Lorenzo ◽  
Fernando J. Lahoz ◽  
Isabel T. Dobrinovitch ◽  
...  
Keyword(s):  
Synthesis And Characterization ◽  
Iridium Complexes ◽  
Michael Reactions

Synthesis and Characterization of Diametrically Substituted Tetra-O-n-butylcalix[4]arene Ligands and Their Chelated Complexes of Titanium, Molybdenum, and Palladium

2002 ◽  
Vol 41 (23) ◽  
pp. 5986-6000 ◽  
Author(s):  
Daniel R. Evans ◽  
Mingsheng Huang ◽  
James C. Fettinger ◽  
Tracie L. Williams
Keyword(s):  
Synthesis And Characterization ◽  
Arene Ligands
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