Formation of Osmium Alkylidene, Alkylidyne, and Dinitrogen Complexes from Reactions of OsCl2(PPh3)3 with Diazoalkanes

2021 ◽  
Author(s):  
Mingxu Cui ◽  
Herman H. Y. Sung ◽  
Ian D. Williams ◽  
Guochen Jia
Keyword(s):  
Dinitrogen Complexes

Theoretical study on dinitrogen complexes. Relation between facility of protonation and difference of electronic structures of d6 and d8 complexes

1984 ◽  
Vol 62 (7) ◽  
pp. 1329-1332 ◽  
Author(s):  
Kenzi Hori ◽  
Tokio Yamabe
Keyword(s):  
Electronic Structures ◽  
Theoretical Study ◽  
Nitrogen Molecule ◽  
Dinitrogen Complexes

Electronic structures of different d configurations have been studied in relation to the facility of protonation to dinitrogen ligand in Cr(0) and Co(I) complexes. The d6 Cr complex has much better MO's for protonation than the d8 Co complex. This difference largely affects the protonation energies and the reduction of nitrogen molecule in these complexes.

Direct formation of acylazo- and aroylazo-rhenium(III) complexes from rhenium(I) dinitrogen complexes

1973 ◽  
Vol 57 (2) ◽  
pp. C67-C68 ◽  
Author(s):  
Joseph Chatt ◽  
Graham A. Heath ◽  
Norman E. Hooper ◽  
G.Jeffery Leigh
Keyword(s):  
Dinitrogen Complexes ◽  
Direct Formation
Sign in / Sign up

Export Citation Format

Share Document