Enhanced Performance of Gadolinia-Doped Ceria Diffusion Barrier Layers Fabricated by Pulsed Laser Deposition for Large-Area Solid Oxide Fuel Cells

2018 ◽  
Vol 1 (5) ◽  
pp. 1955-1964 ◽  
Author(s):  
Miguel Morales ◽  
Arianna Pesce ◽  
Aneta Slodczyk ◽  
Marc Torrell ◽  
Paolo Piccardo ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Solid Oxide Fuel Cells ◽  
Diffusion Barrier ◽  
Pulsed Laser ◽  
Solid Oxide ◽  
Laser Deposition ◽  
Doped Ceria ◽  
Oxide Fuel ◽  
Large Area ◽  
Barrier Layers

scholarly journals Pulsed Laser Deposition of Sm0.2Ce0.8O1.9/Zr0.9Sc0.1O2 Bilayer Films for Fuel Cell Application

2007 ◽  
Vol 539-543 ◽  
pp. 1344-1349
Author(s):  
Dong Fang Yang
Keyword(s):  
Fuel Cells ◽  
Solid Oxide Fuel Cells ◽  
Pulsed Laser Deposition ◽  
Pulsed Laser ◽  
Solid Oxide ◽  
Laser Deposition ◽  
Doped Ceria ◽  
Oxide Fuel ◽  
Bilayer Films ◽  
Reflection Data

Samarium doped ceria exhibits relative high conductivity of 0.1 S/cm at 700 °C and has been considered to be an attractive electrolyte for solid oxide fuel cells operating at the temperature range between 500 to 600 °C. Although the material exhibits better chemical and structural compatibility with electrodes as well as higher ionic conductivity than Yttria-stabilized Zirconia, the reduction of Ce4+ to Ce3+ induces n-type electronic conduction which tends to decrease power output of solid oxide fuel cells. The problem can be eliminated by using a barrier of thin Zr0.9Sc0.1O2 layer deposited over SDC layer as an alternative electrolyte to improve the stability of Samarium doped ceria under reducing atmosphere. In this work, we will report the results on the development of the Pulsed Laser Deposition (PLD) process to fabricate Sm0.2Ce0.8O1.9/Zr0.9Sc0.1O2 bilayer films. Bilayer films with controlled microstructures, density, and interfacial properties were successfully grown by the PLD at various deposition temperatures on Si(100) substartes. X-ray diffraction was used to determine their crystal structures, while the cross section images of the film-film and film-substrate interfaces were examined by field-emission SEM. The film density was calculated from the index of reflection data determined by a fiber-optic spectrophotometer.

La0.6Sr0.4CoO3-  Thin Films Prepared by Pulsed Laser Deposition as Cathodes for Micro-Solid Oxide Fuel Cells

2012 ◽  
Vol 45 (1) ◽  
pp. 333-336 ◽  
Author(s):  
A. Evans ◽  
S. Karalic ◽  
J. Martynczuk ◽  
M. Prestat ◽  
R. Tolke ◽  
...  
Keyword(s):  
Thin Films ◽  
Fuel Cells ◽  
Solid Oxide Fuel Cells ◽  
Pulsed Laser Deposition ◽  
Pulsed Laser ◽  
Solid Oxide ◽  
Laser Deposition ◽  
Oxide Fuel

Pulsed laser deposition of Y-doped BaZrO 3 thin film as electrolyte for low temperature solid oxide fuel cells

CIRP Annals ◽  
2013 ◽  
Vol 62 (1) ◽  
pp. 563-566 ◽  
Author(s):  
Joonho Park ◽  
Jun Yeol Paek ◽  
Ikwhang Chang ◽  
Sanghoon Ji ◽  
Suk Won Cha ◽  
...  
Keyword(s):  
Thin Film ◽  
Fuel Cells ◽  
Low Temperature ◽  
Solid Oxide Fuel Cells ◽  
Pulsed Laser Deposition ◽  
Pulsed Laser ◽  
Solid Oxide ◽  
Laser Deposition ◽  
Oxide Fuel

High performance metal-supported solid oxide fuel cells with Gd-doped ceria barrier layers

2011 ◽  
Vol 196 (22) ◽  
pp. 9459-9466 ◽  
Author(s):  
Trine Klemensø ◽  
Jimmi Nielsen ◽  
Peter Blennow ◽  
Åsa H. Persson ◽  
Tobias Stegk ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Solid Oxide Fuel Cells ◽  
High Performance ◽  
Solid Oxide ◽  
Doped Ceria ◽  
Oxide Fuel ◽  
Barrier Layers

Spray pyrolysis of doped-ceria barrier layers for solid oxide fuel cells

2017 ◽  
Vol 313 ◽  
pp. 168-176 ◽  
Author(s):  
Dagmara Szymczewska ◽  
Aleksander Chrzan ◽  
Jakub Karczewski ◽  
Sebastian Molin ◽  
Piotr Jasinski
Keyword(s):  
Fuel Cells ◽  
Solid Oxide Fuel Cells ◽  
Spray Pyrolysis ◽  
Solid Oxide ◽  
Doped Ceria ◽  
Oxide Fuel ◽  
Barrier Layers
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