Component-Selective Passivation of Li Residues of Ni-Based Cathode Materials by Chemical Mimicry of Solid Electrolyte Interphase Formation

2018 ◽  
Vol 2 (1) ◽  
pp. 217-221
Author(s):  
Gene Jaehyoung Yang ◽  
Yongseon Kim
Keyword(s):  
Solid Electrolyte ◽  
Cathode Materials ◽  
Solid Electrolyte Interphase ◽  
Chemical Mimicry

Improved rate performance of Prussian blue cathode materials for sodium ion batteries induced by ion-conductive solid-electrolyte interphase layer

2018 ◽  
Vol 399 ◽  
pp. 42-48 ◽  
Author(s):  
Haoyu Fu ◽  
Mengyang Xia ◽  
Ruijie Qi ◽  
Xiaoqiang Liang ◽  
Man Zhao ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Prussian Blue ◽  
Cathode Materials ◽  
Solid Electrolyte Interphase ◽  
Sodium Ion ◽  
Interphase Layer ◽  
Sodium Ion Batteries ◽  
Rate Performance

Rational Design of Quasi Zero-Strain NCM Cathode Materials for Minimizing Volume Change Effects in All-Solid-State Batteries

2019 ◽  
Author(s):  
Florian Strauss ◽  
Lea de Biasi ◽  
A-Young Kim ◽  
Jonas Hertle ◽  
Simon Schweidler ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Cathode Materials ◽  
Rational Design ◽  
Electrode Materials ◽  
Cycling Performance ◽  
Mechanical Degradation ◽  
Volume Changes ◽  
Solid State Batteries ◽  
All Solid State Batteries

Measures to improve the cycling performance and stability of bulk-type all-solid-state batteries (SSBs) are currently being developed with the goal of substituting conventional Li-ion battery (LIB) technology. As known from liquid electrolyte based LIBs, layered oxide cathode materials undergo volume changes upon (de)lithiation, causing mechanical degradation due to particle fracture, among others. Unlike solid electrolytes, liquid electrolytes are somewhat capable of accommodating morphological changes. In SSBs, the rigidity of the materials used typically leads to adverse contact loss at the interfaces of cathode material and solid electrolyte during cycling. Hence, designing zero- or low-strain electrode materials for application in next-generation SSBs is desirable. In the present work, we report on novel Co-rich NCMs, NCM361 (60% Co) and NCM271 (70% Co), showing minor volume changes up to 4.5 V vs Li<sup>+</sup>/Li, as determined by <i>operando</i> X-ray diffraction and pressure measurements of LIB pouch and pelletized SSB cells, respectively. Both cathode materials exhibit good cycling performance when incorporated into SSB cells using argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolyte, albeit their morphology and secondary particle size have not yet been optimized.

Rational Design of Quasi Zero-Strain NCM Cathode Materials for Minimizing Volume Change Effects in All-Solid-State Batteries

2019 ◽  
Author(s):  
Florian Strauss ◽  
Lea de Biasi ◽  
A-Young Kim ◽  
Jonas Hertle ◽  
Simon Schweidler ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Cathode Materials ◽  
Rational Design ◽  
Electrode Materials ◽  
Cycling Performance ◽  
Mechanical Degradation ◽  
Volume Changes ◽  
Solid State Batteries ◽  
All Solid State Batteries

Measures to improve the cycling performance and stability of bulk-type all-solid-state batteries (SSBs) are currently being developed with the goal of substituting conventional Li-ion battery (LIB) technology. As known from liquid electrolyte based LIBs, layered oxide cathode materials undergo volume changes upon (de)lithiation, causing mechanical degradation due to particle fracture, among others. Unlike solid electrolytes, liquid electrolytes are somewhat capable of accommodating morphological changes. In SSBs, the rigidity of the materials used typically leads to adverse contact loss at the interfaces of cathode material and solid electrolyte during cycling. Hence, designing zero- or low-strain electrode materials for application in next-generation SSBs is desirable. In the present work, we report on novel Co-rich NCMs, NCM361 (60% Co) and NCM271 (70% Co), showing minor volume changes up to 4.5 V vs Li<sup>+</sup>/Li, as determined by <i>operando</i> X-ray diffraction and pressure measurements of LIB pouch and pelletized SSB cells, respectively. Both cathode materials exhibit good cycling performance when incorporated into SSB cells using argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolyte, albeit their morphology and secondary particle size have not yet been optimized.

scholarly journals Stable Solid Electrolyte Interphase Formation Induced by Monoquat-Based Anchoring in Lithium Metal Batteries

2021 ◽  
pp. 1711-1718
Author(s):  
Tianhong Zhou ◽  
Yan Zhao ◽  
Mario El Kazzi ◽  
Jang Wook Choi ◽  
Ali Coskun
Keyword(s):  
Solid Electrolyte ◽  
Solid Electrolyte Interphase ◽  
Lithium Metal ◽  
Lithium Metal Batteries

Unveiling the Formation of Solid Electrolyte Interphase and its Temperature Dependence in “Water-in-Salt” Supercapacitors

2021 ◽  
Vol 13 (3) ◽  
pp. 3979-3990
Author(s):  
Ting Quan ◽  
Eneli Härk ◽  
Yaolin Xu ◽  
Ibbi Ahmet ◽  
Christian Höhn ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Temperature Dependence ◽  
Solid Electrolyte Interphase

Reactivity and Evolution of Ionic Phases in the Lithium Solid–Electrolyte Interphase

2021 ◽  
pp. 877-885
Author(s):  
Rui Guo ◽  
Dongniu Wang ◽  
Lucia Zuin ◽  
Betar M. Gallant
Keyword(s):  
Solid Electrolyte ◽  
Solid Electrolyte Interphase

scholarly journals Probing the Na metal solid electrolyte interphase via cryo-transmission electron microscopy

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Bing Han ◽  
Yucheng Zou ◽  
Zhen Zhang ◽  
Xuming Yang ◽  
Xiaobo Shi ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Solid Electrolyte ◽  
Solid Electrolyte Interphase ◽  
Metal Electrode ◽  
Liquid Electrolyte ◽  
Battery Materials ◽  
Cryogenic Transmission Electron Microscopy ◽  
Transmission Electron ◽  
Fluoroethylene Carbonate

AbstractCryogenic transmission electron microscopy (cryo-TEM) is a valuable tool recently proposed to investigate battery electrodes. Despite being employed for Li-based battery materials, cryo-TEM measurements for Na-based electrochemical energy storage systems are not commonly reported. In particular, elucidating the chemical and morphological behavior of the Na-metal electrode in contact with a non-aqueous liquid electrolyte solution could provide useful insights that may lead to a better understanding of metal cells during operation. Here, using cryo-TEM, we investigate the effect of fluoroethylene carbonate (FEC) additive on the solid electrolyte interphase (SEI) structure of a Na-metal electrode. Without FEC, the NaPF6-containing carbonate-based electrolyte reacts with the metal electrode to produce an unstable SEI, rich in Na2CO3 and Na3PO4, which constantly consumes the sodium reservoir of the cell during cycling. When FEC is used, the Na-metal electrode forms a multilayer SEI structure comprising an outer NaF-rich amorphous phase and an inner Na3PO4 phase. This layered structure stabilizes the SEI and prevents further reactions between the electrolyte and the Na metal.

Solid Electrolyte Interphase Engineering for Aqueous Aluminum Metal Batteries: A Critical Evaluation

2021 ◽  
pp. 2100077
Author(s):  
Tony Dong ◽  
Kok Long Ng ◽  
Yijia Wang ◽  
Oleksandr Voznyy ◽  
Gisele Azimi
Keyword(s):  
Solid Electrolyte ◽  
Solid Electrolyte Interphase ◽  
Critical Evaluation ◽  
Aluminum Metal ◽  
Aqueous Aluminum

scholarly journals A chemically consistent graph architecture for massive reaction networks applied to solid-electrolyte interphase formation

2021 ◽  
Author(s):  
Samuel M. Blau ◽  
Hetal D Patel ◽  
Evan Walter Clark Spotte-Smith ◽  
Xiaowei Xie ◽  
Shyam Dwaraknath ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid Electrolyte ◽  
Chemical Reaction ◽  
Solid Electrolyte Interphase ◽  
Chemical Reaction Networks ◽  
Reaction Networks ◽  
Mechanistic Understanding

Modeling reactivity with chemical reaction networks could yield fundamental mechanistic understanding that would expedite the development of processes and technologies for energy storage, medicine, catalysis, and more. Thus far, reaction...

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